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Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands.

Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands. Research Abstract Details 

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  • Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands. Abstract Text:

    ho yu au-yeungHo Yu Au-Yeung,chung hei lamChung Hei Lam,chi-keung lamChi-Keung Lam,wai-yeung wongWai-Yeung Wong,hung kay leeHung Kay Lee,

    The coordination chemistry of the N-substituted arylamido ligands [N(R)(C6H3R'2-2,6)] [R = SiMe3, R' = Me (L1); R = CH2But, R' = Pri (L2)] toward FeII and CoII ions was studied. The monoamido complexes [M(L1)(Cl)(tmeda)] [M = Fe (1), Co (2)] react readily with MeLi, affording the mononuclear, paramagnetic iron(II) and cobalt(II) methyl-arylamido complexes [M(L1)(Me)(tmeda)] [M = Fe (3), Co (4)]. Treatment of 2:1 [Li(L2)(THF)2]/FeCl2 affords the unusual two-coordinate iron(II) bis(arylamide) [Fe(L2)2] (5).

    Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands. Publishing Authors By Initials

    hy au-yeungHY Au-Yeung,ch lamCH Lam,ck lamCK Lam,wy wongWY Wong,hk leeHK Lee,

    For similar abstracts research abstracts see: abstracts research

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    Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands. Journal Published:

    PUBLICATION TYPE: Journal Article

    Journal: Inorganic chemistry

    VOLUME: 46

    Page Numbers: 7695-7

    Journal Abbreviation:

    ISSN: 0020-1669

    DAY: 17

    MONTH: 08

    YEAR: 2007

    Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands. Information

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    LANGUAGE: eng

    NlmUniqueID: 366543

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    Grant and Affiliation Information for Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands.

    AFFILIATION: Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, People's Republic of China.

    Country: United States

    United States Research PublicationUnited States Research Publication

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    MEDLINETA: Inorg Chem

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