Total syntheses of (+/-)-beta-erythroidine and (+/-)-8-oxo-beta-erythroidine by an intramolecular Diels-Alder cycloaddition of a 2-amidoacrolein.

Total syntheses of (+/-)-beta-erythroidine and (+/-)-8-oxo-beta-erythroidine by an intramolecular Diels-Alder cycloaddition of a 2-amidoacrolein. Research Abstract Details 

Research Abstract Table of Contents

Jump to the:

Total syntheses of (+/-)-beta-erythroidine and (+/-)-8-oxo-beta-erythroidine by an intramolecular Diels-Alder cycloaddition of a 2-amidoacrolein. Abstract Text:

Yong He,Raymond L Funk,

[reaction: see text] The total syntheses of (+/-)-beta-erythroidine and (+/-)-8-oxo-beta-erythroidine are described. The tetracyclic ring system of the natural products was quickly assembled by a strategy that features a retrocycloaddition/cycloaddition reaction of an amidodioxin, an intramolecular Heck reaction, and a 6pi-electrocyclic ring closure of a dienoic acid.

Total syntheses of (+/-)-beta-erythroidine and (+/-)-8-oxo-beta-erythroidine by an intramolecular Diels-Alder cycloaddition of a 2-amidoacrolein. Publishing Authors By Initials

Y He,RL Funk,

For similar abstracts research abstracts see: abstracts research

PUBMED ID PMID:

MEDLINE DATE:

Total syntheses of (+/-)-beta-erythroidine and (+/-)-8-oxo-beta-erythroidine by an intramolecular Diels-Alder cycloaddition of a 2-amidoacrolein. Journal Published:

PUBLICATION TYPE: Research Support, N.I.H., Extr

Journal: Organic letters

VOLUME: 8

Page Numbers: 3689-92

Journal Abbreviation:

ISSN: 1523-7060

DAY: 17

MONTH: Aug

YEAR: 2006

Total syntheses of (+/-)-beta-erythroidine and (+/-)-8-oxo-beta-erythroidine by an intramolecular Diels-Alder cycloaddition of a 2-amidoacrolein. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 100890393

Total syntheses of (+/-)-beta-erythroidine and (+/-)-8-oxo-beta-erythroidine by an intramolecular Diels-Alder cycloaddition of a 2-amidoacrolein. Keywords Mesh Terms:

KEYWORDS:

MESH TERMS:

Chemical & Substance for Abstract: Total syntheses of (+/-)-beta-erythroidine and (+/-)-8-oxo-beta-erythroidine by an intramolecular Diels-Alder cycloaddition of a 2-amidoacrolein. Information

Substance Name:

Registry Number:

Grant and Affiliation Information for Total syntheses of (+/-)-beta-erythroidine and (+/-)-8-oxo-beta-erythroidine by an intramolecular Diels-Alder cycloaddition of a 2-amidoacrolein.

AFFILIATION: Department of Chemistry, Pennsylvania State University, University Park, Pennsylvania 16802, USA.

Country: United States

AGENCY:

GRANT:

ACRONYM:

MEDLINETA: Org Lett

REFSOURCE:

DATABASENAME:

ACCESSION NUMBER:

Number Hits: 0

Total syntheses of +/--beta-erythroidine and +/--8-oxo-beta-erythroidine by an intramolecular Diels-Alder cycloaddition of a 2-amidoacrolein Related Publications

• 6-Bromomethyl-4H-1,3-dioxin: a versatile bromomethyl vinyl ketone equivalent for heterocycle and carbocycle construction.
• A comparison of human and near-optimal task management behavior.
• A novel genetic model of selective COX-2 inhibition: comparison with COX-2 null mice.
• A strategy for the total synthesis of dragmacidin E. Construction of the core ring system.
• Acute phase proteins do not account for unmeasured anions in critical illness.
• An approach to the total synthesis of welwistatin.
• Association of small CAB-like proteins (SCPs) of Synechocystis sp. PCC 6803 with Photosystem II.
• Development and validation of the GAIN Short Screener (GSS) for internalizing, externalizing and substance use disorders and crime/violence problems among adolescents and adults.
• Diastereoselective synthesis of 2,3,6-trisubstituted tetrahydropyran-4-ones via Prins cyclizations of enecarbamates: a formal synthesis of (+)-ratjadone A.
• ECG monitoring after cardiac surgery: postoperative atrial fibrillation and the atrial electrogram.
• General health measures and long-term survival in patients with head and neck cancer.
• Generation of N-acyliminium ions via intramolecular conjugate addition reactions: a strategy for the total synthesis of nakadomarin A.
• Generation of aza-ortho-xylylenes via ring opening of 2-(2-acylaminophenyl)aziridines: application in the construction of the communesin ring system.
• Health-related quality of life profiles based on survivorship status for head and neck cancer patients.
• Influence of social support on health-related quality of life outcomes in head and neck cancer.
• Patient-reported factors associated with discontinuing employment following head and neck cancer treatment.
• Powassan Virus: Surveys of Human and Animal Sera.
• Prevalence and comorbidity of major internalizing and externalizing problems among adolescents and adults presenting to substance abuse treatment.
• Response to Protocol Review Scenario: Potential complications.
• SUN WORSHIPPING IN PENNSYLVANIA.
• Scoring System for the Severity of the Metabolic Syndrome: 2161: Board #74 June 1 8:00 AM - 9:30 AM.
• Secondary alkyl hydroperoxides as inhibitors and alternate substrates for lipoxygenase.
• Synthesis of indoles via 6pi-electrocyclic ring closures of trienecarbamates.
• Targeted cyclooxygenase gene (ptgs) exchange reveals discriminant isoform functionality.
• The classification of tumors of bone and the presenting clinical symptoms.
• The interaction of co-occurring mental disorders and recovery management checkups on substance abuse treatment participation and recovery.
• Total syntheses of (+/-)-beta-erythroidine and (+/-)-8-oxo-beta-erythroidine by an intramolecular Diels-Alder cycloaddition of a 2-amidoacrolein.
• Total syntheses of (+/-)-cis-trikentrin A and (+/-)-cis-trikentrin B via electrocyclic ring closures of 2,3-divinylpyrrolines.
• Total synthesis of (+/-)-perophoramidine.
• [Not Available.]