Three-dimensional 3d-4f polymers containing heterometallic rings: syntheses, structures, and magnetic properties.

Three-dimensional 3d-4f polymers containing heterometallic rings: syntheses, structures, and magnetic properties. Research Abstract Details 

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Three-dimensional 3d-4f polymers containing heterometallic rings: syntheses, structures, and magnetic properties. Abstract Text:

Yan Ouyang,Wei Zhang,Na Xu,Gong-Feng Xu,Dai-Zheng Liao,Kazuyoshi Yoshimura,Shi-Ping Yan,Peng Cheng,Yan Ouyang,Wei Zhang,Na Xu,Gong-Feng Xu,Dai-Zheng Liao,Kazuyoshi Yoshimura,Shi-Ping Yan,Peng Cheng,Yan Ouyang,Wei Zhang,Na Xu,Gong-Feng Xu,Dai-Zheng Liao,Kazuyoshi Yoshimura,Shi-Ping Yan,Peng Cheng,Yan Ouyang,Wei Zhang,Na Xu,Gong-Feng Xu,Dai-Zheng Liao,Kazuyoshi Yoshimura,Shi-Ping Yan,Peng Cheng,

Two novel three-dimensional (3D) 3d-4f mixed complexes [Ln(H(2)O)(4)][Ni(2)TTHA(SCN)(2)].H(3)O+ [Ln = Pr (1), Ce (2); H(6)TTHA = triethylenetetraaminehexaacetic acid], based on the building blocks of [Ni(2)TTHA(SCN)(2)](4-), were synthesized and characterized by X-ray crystal diffraction and magnetic properties. The single-crystal structures show that these complexes form a 3D framework, comprised of an unusual infinite one-dimensional chain based on heterometallic Ln2Ni2 rings. The temperature-dependent magnetic susceptibilities were analyzed by an approximate model, leading to g = 2.06. Delta = 2.83, zJ' = -0.6 cm-1 for complex 1 and g = 2.07, Delta = 1.00, zJ' = -0.5 cm(-1) for complex 2.

Three-dimensional 3d-4f polymers containing heterometallic rings: syntheses, structures, and magnetic properties. Publishing Authors By Initials

Y Ouyang,W Zhang,N Xu,GF Xu,DZ Liao,K Yoshimura,SP Yan,P Cheng,Y Ouyang,W Zhang,N Xu,GF Xu,DZ Liao,K Yoshimura,SP Yan,P Cheng,Y Ouyang,W Zhang,N Xu,GF Xu,DZ Liao,K Yoshimura,SP Yan,P Cheng,Y Ouyang,W Zhang,N Xu,GF Xu,DZ Liao,K Yoshimura,SP Yan,P Cheng,

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Three-dimensional 3d-4f polymers containing heterometallic rings: syntheses, structures, and magnetic properties. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Inorganic chemistry

VOLUME: 46

Page Numbers: 8454-6

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ISSN: 0020-1669

DAY: 14

MONTH: 09

YEAR: 2007

Three-dimensional 3d-4f polymers containing heterometallic rings: syntheses, structures, and magnetic properties. Information

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LANGUAGE: eng

NlmUniqueID: 366543

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Grant and Affiliation Information for Three-dimensional 3d-4f polymers containing heterometallic rings: syntheses, structures, and magnetic properties.

AFFILIATION: Department of Chemistry, Nankai University, Tianjin 300071, China.

Country: United States

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MEDLINETA: Inorg Chem

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