Thiolsulfonate functionalized polystyrene resin: preparation and application in the isolation and identification of electrophilic mutagens.

Thiolsulfonate functionalized polystyrene resin: preparation and application in the isolation and identification of electrophilic mutagens. Research Abstract Details 

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Thiolsulfonate functionalized polystyrene resin: preparation and application in the isolation and identification of electrophilic mutagens. Abstract Text:

E Wu,Robert M Carlson,E Wu,Robert M Carlson,

A new approach for isolation and identification of elecrtophilic mutagens from complex matrix was developed. Thiosulfonic anion was immobilized onto polystyrene beads and used as separation media. Potassium polystyryl-thiosulfonate, prepared from polystyrylsulfonyl chloride and KHS, was observed to selectively react with model electrophilic mutagens such as alkyl halides, a-chloroketones and alpha-chloroesters to produce polystyryl-thiosulfonic esters. After separation from other nonreactive organic compounds, the beads then reacted with ethanethiol to produce unsymmetrical ethyl disulfides which are easily detected by GC/MS. For one mutagenic compound, only one unsymmetrical disulfide was found to contain its structure part. Thus, the structure of the parent mutagens could be deduced from that of the unsymmetrical disulfides. The degree of functionalization of the potassium polystyryl-thiosulfonate resin was 1.11 mmol/g. Its reactivity was discussed and its recycling method was reported here.

Thiolsulfonate functionalized polystyrene resin: preparation and application in the isolation and identification of electrophilic mutagens. Publishing Authors By Initials

E Wu,RM Carlson,E Wu,RM Carlson,

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Thiolsulfonate functionalized polystyrene resin: preparation and application in the isolation and identification of electrophilic mutagens. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of environmental sciences (China)

VOLUME: 19

Page Numbers: 1520-7

Journal Abbreviation: J Environ Sci (China)

ISSN: 1001-0742

DAY: 18

MONTH: 02

YEAR: 2007

Thiolsulfonate functionalized polystyrene resin: preparation and application in the isolation and identification of electrophilic mutagens. Information

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LANGUAGE: eng

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Grant and Affiliation Information for Thiolsulfonate functionalized polystyrene resin: preparation and application in the isolation and identification of electrophilic mutagens.

AFFILIATION: Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. weiwob@gmail.com

Country: Netherlands

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MEDLINETA: J Environ Sci (China)

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