The first examples of germanium tetrafluoride and tin tetrafluoride complexes with soft thioether coordination-synthesis, properties and crystal structures.

The first examples of germanium tetrafluoride and tin tetrafluoride complexes with soft thioether coordination-synthesis, properties and crystal structures. Research Abstract Details 

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The first examples of germanium tetrafluoride and tin tetrafluoride complexes with soft thioether coordination-synthesis, properties and crystal structures. Abstract Text:

Martin F Davis,William Levason,Gillian Reid,Michael Webster,Wenjian Zhang,

The first thioether complexes of the hard Lewis acidic GeF(4) and SnF(4) have been prepared by reaction of [GeF(4)(MeCN)(2)] or [SnF(4)(MeCN)(2)] respectively with the thioether ligand in rigorously anhydrous CH(2)Cl(2) solution. The isolated compounds were characterised spectroscopically (IR, (1)H and (19)F{(1)H} NMR) and by microanalyses. Crystal structures of four representative examples, [GeF(4){MeS(CH(2))(2)SMe}], [GeF(4){EtS(CH(2))(2)SEt}], [SnF(4){EtS(CH(2))(2)SEt}] and [SnF(4){(i)PrS(CH(2))(2)S(i)Pr}], reveal distorted octahedral adducts with chelating thioethers, and weak, secondary Ge-S and Sn-S bonds. These compounds are the first reported examples of thioether complexes with any main group metal/metalloid fluoride acceptor.

The first examples of germanium tetrafluoride and tin tetrafluoride complexes with soft thioether coordination-synthesis, properties and crystal structures. Publishing Authors By Initials

MF Davis,W Levason,G Reid,M Webster,W Zhang,

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The first examples of germanium tetrafluoride and tin tetrafluoride complexes with soft thioether coordination-synthesis, properties and crystal structures. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Dalton transactions (Cambridge, England : 2003)

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Page Numbers: 533-8

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ISSN: 1477-9226

DAY: 9

MONTH: 11

YEAR: 2007

The first examples of germanium tetrafluoride and tin tetrafluoride complexes with soft thioether coordination-synthesis, properties and crystal structures. Information

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LANGUAGE: eng

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Grant and Affiliation Information for The first examples of germanium tetrafluoride and tin tetrafluoride complexes with soft thioether coordination-synthesis, properties and crystal structures.

AFFILIATION: School of Chemistry, University of Southampton, Southampton, UKSO17 1BJ. G.Reid@soton.ac.uk.

Country: England

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MEDLINETA: Dalton Trans

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