Tetraalkylphosphonium polyoxometalate ionic liquids: novel, organic-inorganic hybrid materials.

Tetraalkylphosphonium polyoxometalate ionic liquids: novel, organic-inorganic hybrid materials. Research Abstract Details 

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Tetraalkylphosphonium polyoxometalate ionic liquids: novel, organic-inorganic hybrid materials. Abstract Text:

Paul G Rickert,Mark R Antonio,Millicent A Firestone,Karrie-Ann Kubatko,Tomasz Szreder,James F Wishart,Mark L Dietz,

Pairing of a Keggin or Lindqvist polyoxometalate (POM) anion with an appropriate tetraalkylphosphonium cation is shown to yield the first members of a new family of ionic liquids (ILs). Detailed characterization of one of them, an ambient-temperature "liquid POM" comprising the Lindqvist salt of the trihexyl(tetradecyl) phosphonium cation, by voltammetry, viscometry, conductimetry, and thermal analysis indicates that it exhibits conductivity and viscosity comparable to those of the one previously described inorganic-organic POM-IL hybrid but with substantially improved thermal stability.

Tetraalkylphosphonium polyoxometalate ionic liquids: novel, organic-inorganic hybrid materials. Publishing Authors By Initials

PG Rickert,MR Antonio,MA Firestone,KA Kubatko,T Szreder,JF Wishart,ML Dietz,

For similar investigative techniques: chemistry, analytical: crystallography: x-ray diffraction research abstracts see: investigative techniques: chemistry, analytical: crystallography: x-ray diffraction research

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Tetraalkylphosphonium polyoxometalate ionic liquids: novel, organic-inorganic hybrid materials. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: The journal of physical chemistry. B

VOLUME: 111

Page Numbers: 4685-92

Journal Abbreviation:

ISSN: 1520-6106

DAY: 10

MONTH: May

YEAR: 2007

Tetraalkylphosphonium polyoxometalate ionic liquids: novel, organic-inorganic hybrid materials. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 101157530

Tetraalkylphosphonium polyoxometalate ionic liquids: novel, organic-inorganic hybrid materials. Keywords Mesh Terms:

KEYWORDS: X-Ray Diffraction

MESH TERMS: chemistry

Chemical & Substance for Abstract: Tetraalkylphosphonium polyoxometalate ionic liquids: novel, organic-inorganic hybrid materials. Information

Substance Name: sodium tungstate(VI)

Registry Number: 13472-45-2

Grant and Affiliation Information for Tetraalkylphosphonium polyoxometalate ionic liquids: novel, organic-inorganic hybrid materials.

AFFILIATION: Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439, USA.

Country: United States

AGENCY: United States NCRR

GRANT: P41RR0954

ACRONYM: RR

MEDLINETA: J Phys Chem B

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