Tandem pinacol coupling-rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate.

Tandem pinacol coupling-rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate. Research Abstract Details 

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Tandem pinacol coupling-rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate. Abstract Text:

Olena Branytska,Linda J W Shimon,Ronny Neumann,

Together with a strongly oxidizing polyoxometalate, H(5)PV(2)Mo(10)O(40), Pt(II)(N-(2,6-diisopropylphenyl)pyrazin-2-ylmethanimine)Cl2 forms a combined catalyst that was active in the tandem pinacol coupling-rearrangement of aryl aldehydes to give mostly the corresponding diarylacetaldehyde in high yields using molecular hydrogen as the reducing agent.

Tandem pinacol coupling-rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate. Publishing Authors By Initials

O Branytska,LJ Shimon,R Neumann,

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Tandem pinacol coupling-rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Chemical communications (Cambridge, England)

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Page Numbers: 3957-9

Journal Abbreviation: Chem. Commun. (Camb.)

ISSN: 1359-7345

DAY: 20

MONTH: 08

YEAR: 2007

Tandem pinacol coupling-rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate. Information

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LANGUAGE: eng

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AFFILIATION: Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, Israel76100.

Country: England

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MEDLINETA: Chem Commun (Camb)

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