Synthesis, structure, and reactivity of a dinuclear metal complex with linear M-H-M bonding.

Synthesis, structure, and reactivity of a dinuclear metal complex with linear M-H-M bonding. Research Abstract Details 

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Synthesis, structure, and reactivity of a dinuclear metal complex with linear M-H-M bonding. Abstract Text:

David A Vicic,Thomas J Anderson,John A Cowan,Arthur J Schultz,

Reaction of two equiv of 1-adamantylzinc bromide with (dippm)NiBr2 (dippm = bis(di-isopropylphosphino)methane) led to a dinuclear metal complex containing a unique linear bridging hydride ligand. The hydride was characterized by neutron diffraction methods, which confirmed a linear bonding mode. Preliminary reactivity studies of this unusual dimer are reported.

Synthesis, structure, and reactivity of a dinuclear metal complex with linear M-H-M bonding. Publishing Authors By Initials

DA Vicic,TJ Anderson,JA Cowan,AJ Schultz,

For similar organic chemicals: organometallic compounds research abstracts see: organic chemicals: organometallic compounds research

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Synthesis, structure, and reactivity of a dinuclear metal complex with linear M-H-M bonding. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Journal of the American Chemical Society

VOLUME: 126

Page Numbers: 8132-3

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 7

MONTH: Jul

YEAR: 2004

Synthesis, structure, and reactivity of a dinuclear metal complex with linear M-H-M bonding. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

Synthesis, structure, and reactivity of a dinuclear metal complex with linear M-H-M bonding. Keywords Mesh Terms:

KEYWORDS: Organometallic Compounds

MESH TERMS: chemistry

Chemical & Substance for Abstract: Synthesis, structure, and reactivity of a dinuclear metal complex with linear M-H-M bonding. Information

Substance Name: Nickel

Registry Number: 7440-02-0

Grant and Affiliation Information for Synthesis, structure, and reactivity of a dinuclear metal complex with linear M-H-M bonding.

AFFILIATION: Department of Chemistry and Biochemistry, University of Arkansas, Fayetteville, AR 72701, USA. dvicic@uark.edu

Country: United States

AGENCY: United States NCRR

GRANT: RR 15569

ACRONYM: RR

MEDLINETA: J Am Chem Soc

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