Synthesis, spectral, catalytic and antimicrobial studies of PPh3/AsPh3 complexes of Ru(II) with dibasic tridentate O, N, S donor ligands.

Synthesis, spectral, catalytic and antimicrobial studies of PPh3/AsPh3 complexes of Ru(II) with dibasic tridentate O, N, S donor ligands. Research Abstract Details 

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Synthesis, spectral, catalytic and antimicrobial studies of PPh3/AsPh3 complexes of Ru(II) with dibasic tridentate O, N, S donor ligands. Abstract Text:

K P Balasubramanian,R Karvembu,R Prabhakaran,V Chinnusamy,K Natarajan,K P Balasubramanian,R Karvembu,R Prabhakaran,V Chinnusamy,K Natarajan,

Complexes of the type [Ru(CO)(EPh(3))(B)(L)] (E = P or As; B = PPh(3), AsPh(3), py or pip; L=dianion of the Schiff bases derived from thiosemicarbazone with acetoacetanilide, acetoacet-o-toluidide and o-chloro acetoacetanilide) have been synthesized from the reactions of equimolar amounts of [RuHCl(CO)(EPh(3))(2)(B)] and Schiff bases in benzene. The new complexes have been characterized by analytical and spectral (IR, electronic, NMR) data. The arrangement of PPh(3) groups around ruthenium metal was determined from (31)P NMR spectra. An octahedral structure has been assigned for all the new complexes. All the complexes exhibited catalytic activity for the oxidation of benzyl alcohol and cyclohexanol in presence of N-methylmorpholine-N-oxide as co-oxidant. The complexes also exhibited antibacterial activity against E. coli, Aeromonas hydrophilla and Salmonella typhi. The activity was compared with standard streptomycin.

Synthesis, spectral, catalytic and antimicrobial studies of PPh3/AsPh3 complexes of Ru(II) with dibasic tridentate O, N, S donor ligands. Publishing Authors By Initials

KP Balasubramanian,R Karvembu,R Prabhakaran,V Chinnusamy,K Natarajan,KP Balasubramanian,R Karvembu,R Prabhakaran,V Chinnusamy,K Natarajan,

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Synthesis, spectral, catalytic and antimicrobial studies of PPh3/AsPh3 complexes of Ru(II) with dibasic tridentate O, N, S donor ligands. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Spectrochimica acta. Part A, Molecular and biomole

VOLUME: 68

Page Numbers: 50-4

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ISSN: 1386-1425

DAY: 6

MONTH: 11

YEAR: 2006

Synthesis, spectral, catalytic and antimicrobial studies of PPh3/AsPh3 complexes of Ru(II) with dibasic tridentate O, N, S donor ligands. Information

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LANGUAGE: eng

NlmUniqueID: 9602533

Synthesis, spectral, catalytic and antimicrobial studies of PPh3/AsPh3 complexes of Ru(II) with dibasic tridentate O, N, S donor ligands. Keywords Mesh Terms:

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Grant and Affiliation Information for Synthesis, spectral, catalytic and antimicrobial studies of PPh3/AsPh3 complexes of Ru(II) with dibasic tridentate O, N, S donor ligands.

AFFILIATION: Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore 641 020, India.

Country: England

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MEDLINETA: Spectrochim Acta A Mol Biomol

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