[Synthesis, spectra, nonlinear optical properties and theoretical calculations of metal complexes containing phenothiazine ligand]

[Synthesis, spectra, nonlinear optical properties and theoretical calculations of metal complexes containing phenothiazine ligand] Research Abstract Details 

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[Synthesis, spectra, nonlinear optical properties and theoretical calculations of metal complexes containing phenothiazine ligand] Abstract Text:

Zhao-ming Xue,Xuan-jun Zhang,Yu-peng Tian,

A new ligand, S-benzyl-(-N-[10-ethylphenothiazinyl-3yl]-methylene] dithiocarbazate (abbreviated as HL), and its complexes ML2 (M=Co and Hg) have been synthesized and fully characterized by elemental analyses, EI-MS, 1H NMR, IR, UV-Vis spectra, and photoluminescence measurement. All of the compounds emit an olivine color in DMF solution. The emission maximum (lambdamax(em)), and fluorescence quantum (phif) of each compound were measured. Nonlinear Optical properties of the HL and ML2 were studied by z-scan technique. Nonlinear absorption coefficient beta were measured to be 0.71, 0.19 and 0.395 cm x GW(-1). Theoretical calculations (RHF/PM3) were consistent with the experimental results.

[Synthesis, spectra, nonlinear optical properties and theoretical calculations of metal complexes containing phenothiazine ligand] Publishing Authors By Initials

ZM Xue,XJ Zhang,YP Tian,

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[Synthesis, spectra, nonlinear optical properties and theoretical calculations of metal complexes containing phenothiazine ligand] Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: Guang pu xue yu guang pu fen xi = Guang pu

VOLUME: 24

Page Numbers: 704-7

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ISSN: 1000-0593

DAY: 15

MONTH: Jun

YEAR: 2004

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LANGUAGE: chi

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AFFILIATION: Department of Chemistry, Anhui University, Hefei 230039, China.

Country: China

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MEDLINETA: Guang Pu Xue Yu Guang Pu Fen X

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