A new synthetic method of substituted furoates from acrylates and aldehydes was developed by Pd(OAc)2 combined with molybdovanadophosphoric acid and Lewis acid under atmospheric dioxygen. The reaction was found to proceed through the palladium-catalyzed acetalization of acrylates with methanol followed by the reaction of the resulting acetals with aldehydes.
Synthesis of substituted furoates from acrylates and aldehydes by Pd(OAc)(2)/HPMoV/CeCl(3)/O(2) system. Publishing Authors By Initials
Synthesis of substituted furoates from acrylates and aldehydes by Pd(OAc)(2)/HPMoV/CeCl(3)/O(2) system. Journal Published:
PUBLICATION TYPE: Research Support, Non-U.S. Gov
Journal: The Journal of organic chemistry
VOLUME: 72
Page Numbers: 8820-3
Journal Abbreviation: J. Org. Chem.
ISSN: 0022-3263
DAY: 18
MONTH: 10
YEAR: 2007
Synthesis of substituted furoates from acrylates and aldehydes by Pd(OAc)(2)/HPMoV/CeCl(3)/O(2) system. Information
Number of References:
LANGUAGE: eng
NlmUniqueID: 2985193
Synthesis of substituted furoates from acrylates and aldehydes by Pd(OAc)(2)/HPMoV/CeCl(3)/O(2) system. Keywords Mesh Terms:
KEYWORDS:
MESH TERMS:
Chemical & Substance for Abstract: Synthesis of substituted furoates from acrylates and aldehydes by Pd(OAc)(2)/HPMoV/CeCl(3)/O(2) system. Information
Substance Name:
Registry Number:
Grant and Affiliation Information for Synthesis of substituted furoates from acrylates and aldehydes by Pd(OAc)(2)/HPMoV/CeCl(3)/O(2) system.
AFFILIATION: Department of Chemistry and Material Engineering, Faculty of Chemistry, Materials and Bioengineering and High Technology Research Center, Kansai University, Suita, Osaka, Japan.
Country: United States
AGENCY:
GRANT:
ACRONYM:
MEDLINETA: J Org Chem
REFSOURCE:
DATABASENAME:
ACCESSION NUMBER:
Number Hits: 0
Synthesis of substituted furoates from acrylates and aldehydes by PdOAc2/HPMoV/CeCl3/O2 system Related Publications