Synthesis and structure of Ag(1-Me-12-SiPh3-CB11F10): selective F12 substitution in 1-Me-CB11F11- and the first Ag(arene)4+ tetrahedron.

Synthesis and structure of Ag(1-Me-12-SiPh3-CB11F10): selective F12 substitution in 1-Me-CB11F11- and the first Ag(arene)4+ tetrahedron. Research Abstract Details 

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Synthesis and structure of Ag(1-Me-12-SiPh3-CB11F10): selective F12 substitution in 1-Me-CB11F11- and the first Ag(arene)4+ tetrahedron. Abstract Text:

Yoshihiro Kobayashi,Alexey A Popov,Susie M Miller,Oren P Anderson,Steven H Strauss,Yoshihiro Kobayashi,Alexey A Popov,Susie M Miller,Oren P Anderson,Steven H Strauss,Yoshihiro Kobayashi,Alexey A Popov,Susie M Miller,Oren P Anderson,Steven H Strauss,Yoshihiro Kobayashi,Alexey A Popov,Susie M Miller,Oren P Anderson,Steven H Strauss,

The selective substitution of the antipodal F atom in 1-Me-CB(11)F(11)- with a SiPh(3) moiety led to the isolation and structure determination of the cesium(I) and silver(I) salts of the 1-Me-12-SiPh(3)-CB(11)F(10)- anion. The silver salt contains both a nearly trigonal-planar Ag(arene)(3)+ cation and the first example of a Ag(arene)(4)+ cation.

Synthesis and structure of Ag(1-Me-12-SiPh3-CB11F10): selective F12 substitution in 1-Me-CB11F11- and the first Ag(arene)4+ tetrahedron. Publishing Authors By Initials

Y Kobayashi,AA Popov,SM Miller,OP Anderson,SH Strauss,Y Kobayashi,AA Popov,SM Miller,OP Anderson,SH Strauss,Y Kobayashi,AA Popov,SM Miller,OP Anderson,SH Strauss,Y Kobayashi,AA Popov,SM Miller,OP Anderson,SH Strauss,

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Synthesis and structure of Ag(1-Me-12-SiPh3-CB11F10): selective F12 substitution in 1-Me-CB11F11- and the first Ag(arene)4+ tetrahedron. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Inorganic chemistry

VOLUME: 46

Page Numbers: 8505-7

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ISSN: 0020-1669

DAY: 21

MONTH: 09

YEAR: 2007

Synthesis and structure of Ag(1-Me-12-SiPh3-CB11F10): selective F12 substitution in 1-Me-CB11F11- and the first Ag(arene)4+ tetrahedron. Information

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LANGUAGE: eng

NlmUniqueID: 366543

Synthesis and structure of Ag(1-Me-12-SiPh3-CB11F10): selective F12 substitution in 1-Me-CB11F11- and the first Ag(arene)4+ tetrahedron. Keywords Mesh Terms:

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Grant and Affiliation Information for Synthesis and structure of Ag(1-Me-12-SiPh3-CB11F10): selective F12 substitution in 1-Me-CB11F11- and the first Ag(arene)4+ tetrahedron.

AFFILIATION: Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.

Country: United States

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MEDLINETA: Inorg Chem

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