Synthesis and characterization of hydroxy-functionalized models for the active site in Fe-only-hydrogenases.

Synthesis and characterization of hydroxy-functionalized models for the active site in Fe-only-hydrogenases. Research Abstract Details 

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Synthesis and characterization of hydroxy-functionalized models for the active site in Fe-only-hydrogenases. Abstract Text:

Ulf-Peter Apfel,Yvonne Halpin,Helmar ,Johannes G Vos,Bernd Schweizer,Gerald Linti,Wolfgang Weigand,

The reactions of DL-1,4-disulfanylbutane-2,3-diol and 1,3-disulfanylpropan-2-ol with dodecacarbonyltriiron have been investigated. As main products, the iron complexes 1 and 2 were isolated and characterized by spectroscopic methods, as well as single crystal X-ray analysis. Additionally, the unusually large bond angles in the dithiolato bridge was investigated via density-functional theory (DFT) calculations. Moreover, the electrochemical features have been studied by cyclic voltammetry.

Synthesis and characterization of hydroxy-functionalized models for the active site in Fe-only-hydrogenases. Publishing Authors By Initials

UP Apfel,Y Halpin,H ,JG Vos,B Schweizer,G Linti,W Weigand,

For similar organic chemicals: organometallic compounds research abstracts see: organic chemicals: organometallic compounds research

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Synthesis and characterization of hydroxy-functionalized models for the active site in Fe-only-hydrogenases. Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: Chemistry & biodiversity

VOLUME: 4

Page Numbers: 2138-48

Journal Abbreviation: Chem. Biodivers.

ISSN: 1612-1880

DAY: 20

MONTH: Sep

YEAR: 2007

Synthesis and characterization of hydroxy-functionalized models for the active site in Fe-only-hydrogenases. Information

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LANGUAGE: eng

NlmUniqueID: 101197449

Synthesis and characterization of hydroxy-functionalized models for the active site in Fe-only-hydrogenases. Keywords Mesh Terms:

KEYWORDS: Organometallic Compounds

MESH TERMS: chemistry

Chemical & Substance for Abstract: Synthesis and characterization of hydroxy-functionalized models for the active site in Fe-only-hydrogenases. Information

Substance Name: Hydrogenase

Registry Number: EC 1.18.99.1

Grant and Affiliation Information for Synthesis and characterization of hydroxy-functionalized models for the active site in Fe-only-hydrogenases.

AFFILIATION: Friedrich-Schiller Universität Jena, August Bebel-Strasse 2, D-07743 Jena.

Country: Switzerland

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MEDLINETA: Chem Biodivers

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