Synergy between spin crossover and metallophilicity in triple interpenetrated 3D nets with the NbO structure type.

Synergy between spin crossover and metallophilicity in triple interpenetrated 3D nets with the NbO structure type. Research Abstract Details 

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Synergy between spin crossover and metallophilicity in triple interpenetrated 3D nets with the NbO structure type. Abstract Text:

Ana Galet,Virginie Niel,M Carmen , Real,

Self-assembly of [Ag(CN)2]-, 3-cyanopyridine, and iron(II) gives triple interpenetration of three-dimensional spin crossover (SCO) networks with the NbO topology, which interact each other via argentophilic interactions. Superposition of the networks along the c-axis defines an infinite mosaic of trigonal and hexagonal cross-sectional tubes where water molecules are installed. The structural changes associated with the SCO tune the homoatomic interactions and induce an uncommon change of the lattice volume.

Synergy between spin crossover and metallophilicity in triple interpenetrated 3D nets with the NbO structure type. Publishing Authors By Initials

A Galet,V Niel,MC ,JA Real,

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Synergy between spin crossover and metallophilicity in triple interpenetrated 3D nets with the NbO structure type. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 125

Page Numbers: 14224-5

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 26

MONTH: Nov

YEAR: 2003

Synergy between spin crossover and metallophilicity in triple interpenetrated 3D nets with the NbO structure type. Information

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LANGUAGE: eng

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Grant and Affiliation Information for Synergy between spin crossover and metallophilicity in triple interpenetrated 3D nets with the NbO structure type.

AFFILIATION: Departament de Física Aplicada, Universitat Politècnica de València, Camino de Vera s/n, 46022 València, Spain.

Country: United States

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