Synergistic effect between metal coordination and hydrogen bonding in phosphate and halide recognition.

Synergistic effect between metal coordination and hydrogen bonding in phosphate and halide recognition. Research Abstract Details 

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Synergistic effect between metal coordination and hydrogen bonding in phosphate and halide recognition. Abstract Text:

Jik Chin,Suhman Chung,Dong H Kim,

The equilibrium constant for binding of dimethyl phosphate to a Co(III) complex in water increases from 6.2 to 210 M-1 upon addition of a single hydrogen bond between the bound phosphate and the metal complex. Crystal structure reveals that the hydrogen bond distance is 1.96 A. The synergistic effect between metal coordination and hydrogen bonding can also be observed for fluoride binding but not for bromide binding.

Synergistic effect between metal coordination and hydrogen bonding in phosphate and halide recognition. Publishing Authors By Initials

J Chin,S Chung,DH Kim,

For similar investigative techniques: chemistry, analytical: titrimetry: potentiometry research abstracts see: investigative techniques: chemistry, analytical: titrimetry: potentiometry research

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Synergistic effect between metal coordination and hydrogen bonding in phosphate and halide recognition. Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: Journal of the American Chemical Society

VOLUME: 124

Page Numbers: 10948-9

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 18

MONTH: Sep

YEAR: 2002

Synergistic effect between metal coordination and hydrogen bonding in phosphate and halide recognition. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

Synergistic effect between metal coordination and hydrogen bonding in phosphate and halide recognition. Keywords Mesh Terms:

KEYWORDS: Potentiometry

MESH TERMS: chemistry

Chemical & Substance for Abstract: Synergistic effect between metal coordination and hydrogen bonding in phosphate and halide recognition. Information

Substance Name: Cobalt

Registry Number: 7440-48-4

Grant and Affiliation Information for Synergistic effect between metal coordination and hydrogen bonding in phosphate and halide recognition.

AFFILIATION: Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario, Canada M5S 3H6. jchin@chem.utoronto.ca

Country: United States

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MEDLINETA: J Am Chem Soc

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