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Synchrotron X-ray Imaging of the Electron Density in RFeO(3) (R = Y, Ho) Using an APD Detector.

Synchrotron X-ray Imaging of the Electron Density in RFeO(3) (R = Y, Ho) Using an APD Detector. Research Abstract Details 

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  • Synchrotron X-ray Imaging of the Electron Density in RFeO(3) (R = Y, Ho) Using an APD Detector. Abstract Text:

    v a streltsovV A Streltsov,n ishizawaN Ishizawa,s kishimotoS Kishimoto,

    Structure factors for small hydrothermally grown yttrium and holmium orthoferrites, RFeO(3) (R = Y, Ho), were measured with focused synchrotron radiation at wavelengths of 0.70 and 0.84 A using both scintillation and high-speed avalanche photodiode (APD) detectors. Resulting APD Deltarho images showed striking correlations between aspherical electron densities around Fe and rare-earth metals. Approximate high symmetry in the Deltarho images indicates that cations deform the electron density far more strongly than the O atoms. The Ho-Fe magnetic interactions appear to affect the electron density distribution of the Fe atoms and the magnetic phase transitions. Space group Pnma, orthorhombic, YFeO(3) (APD): M(r) = 192.76, a = 5.5931 (3), b = 7.6102 (4), c = 5.2806 (3) A, V = 224.77 (2) A(3), Z = 4, D(x) = 5.695 Mg m(-3), mu(0.84) = 15.56 mm(-1), F(000) = 356, T = 293 K, R = 0.045, wR = 0.073, S = 4.83 (9) for 1282 unique reflections; HoFeO(3) (APD): M(r) = 268.78, a = 5.5922 (3), b = 7.6157 (5), c = 5.2798 (3) A, V = 224.86 (2) A(3), Z = 4, D(x) = 7.939 Mg m(-3), mu(0.84) = 61.98 mm(-1), F(000) = 356, T = 293 K, R = 0.036, wR = 0.037, S = 3.07 (6) for 1284 unique reflections.

    Synchrotron X-ray Imaging of the Electron Density in RFeO(3) (R = Y, Ho) Using an APD Detector. Publishing Authors By Initials

    va streltsovVA Streltsov,n ishizawaN Ishizawa,s kishimotoS Kishimoto,

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    Synchrotron X-ray Imaging of the Electron Density in RFeO(3) (R = Y, Ho) Using an APD Detector. Journal Published:

    PUBLICATION TYPE: Journal Article

    Journal: Journal of synchrotron radiation

    VOLUME: 5

    Page Numbers: 1309-16

    Journal Abbreviation:

    ISSN: 0909-0495

    DAY: 1

    MONTH: Sep

    YEAR: 1998

    Synchrotron X-ray Imaging of the Electron Density in RFeO(3) (R = Y, Ho) Using an APD Detector. Information

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    LANGUAGE: eng

    NlmUniqueID: 9888878

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    Grant and Affiliation Information for Synchrotron X-ray Imaging of the Electron Density in RFeO(3) (R = Y, Ho) Using an APD Detector.

    AFFILIATION: Crystallography Centre, The University of Western Australia, Nedlands 6907, Australia.

    Country: Denmark

    Denmark Research PublicationDenmark Research Publication

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    MEDLINETA: J Synchrotron Radiat

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