Study of the dissociation of nitrous oxide following resonant excitation of the nitrogen and oxygen K-shells.

Study of the dissociation of nitrous oxide following resonant excitation of the nitrogen and oxygen K-shells. Research Abstract Details 

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Study of the dissociation of nitrous oxide following resonant excitation of the nitrogen and oxygen K-shells. Abstract Text:

D ,O Travnikova,Z Bao,M N Piancastelli,T Tanaka,M Hoshino,H Kato,H Tanaka,J R Harries,Y Tamenori,C ,T Lischke,X-J Liu,K Ueda,D Céolin,O Travnikova,Z Bao,M N Piancastelli,T Tanaka,M Hoshino,H Kato,H Tanaka,J R Harries,Y Tamenori,C Prümper,T Lischke,X-J Liu,K Ueda,D ,O Travnikova,Z Bao,M N Piancastelli,T Tanaka,M Hoshino,H Kato,H Tanaka,J R Harries,Y Tamenori,C ,T Lischke,X-J Liu,K Ueda,

A photochemistry study on nitrous oxide making use of site-selective excitation of terminal nitrogen, central nitrogen, and oxygen 1s-->3pi excitations is presented. The resonant Auger decay which takes place following excitation can lead to dissociation of the N(2)O(+) ion. To elucidate the nuclear dynamics, energy-resolved Auger electrons were detected in coincidence with the ionic dissociation products, and a strong dependence of the fragmentation pathways on the core-hole site was observed in the binding energy region of the first satellite states. A description based on the molecular orbitals as well as the correlation between the thermodynamical thresholds of ion formation and the first electronic states of N(2)O(+) has been used to qualitatively explain the observed fragmentation patterns.

Study of the dissociation of nitrous oxide following resonant excitation of the nitrogen and oxygen K-shells. Publishing Authors By Initials

D ,O Travnikova,Z Bao,MN Piancastelli,T Tanaka,M Hoshino,H Kato,H Tanaka,JR Harries,Y Tamenori,C ,T Lischke,XJ Liu,K Ueda,D Céolin,O Travnikova,Z Bao,MN Piancastelli,T Tanaka,M Hoshino,H Kato,H Tanaka,JR Harries,Y Tamenori,C Prümper,T Lischke,XJ Liu,K Ueda,D ,O Travnikova,Z Bao,MN Piancastelli,T Tanaka,M Hoshino,H Kato,H Tanaka,JR Harries,Y Tamenori,C ,T Lischke,XJ Liu,K Ueda,

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Study of the dissociation of nitrous oxide following resonant excitation of the nitrogen and oxygen K-shells. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: The Journal of chemical physics

VOLUME: 128

Page Numbers: 024306

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ISSN: 0021-9606

DAY: 14

MONTH: Jan

YEAR: 2008

Study of the dissociation of nitrous oxide following resonant excitation of the nitrogen and oxygen K-shells. Information

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LANGUAGE: eng

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Grant and Affiliation Information for Study of the dissociation of nitrous oxide following resonant excitation of the nitrogen and oxygen K-shells.

AFFILIATION: Department of Synchrotron Radiation Research, Institute of Physics, University of Lund, P.O. Box 118, SE-221 00 Lund, Sweden and Department of Physics, Uppsala University, P.O. Box 530, SE-75121 Uppsala, Sweden.

Country: United States

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MEDLINETA: J Chem Phys

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