A synthesis of the C(1)-C(11) fragment of apoptolidin A has been accomplished by a convergent route involving the stereoselective glycosidation of 9 and the Suzuki cross-coupling reaction of bromodienoate 7 and the vinylborane generated via chemoselective hydroboration of diyne 6 with diisopinocampheylborane.
Studies on the synthesis of apoptolidin a. 1. Synthesis of the c(1)-c(11) fragment. Publishing Authors By Initials
Studies on the synthesis of apoptolidin a. 1. Synthesis of the c(1)-c(11) fragment. Journal Published:
PUBLICATION TYPE: Journal Article
Journal: The Journal of organic chemistry
VOLUME: 73
Page Numbers: 1031-5
Journal Abbreviation: J. Org. Chem.
ISSN: 0022-3263
DAY: 29
MONTH: 12
YEAR: 2007
Studies on the synthesis of apoptolidin a. 1. Synthesis of the c(1)-c(11) fragment. Information
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LANGUAGE: eng
NlmUniqueID: 2985193
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Grant and Affiliation Information for Studies on the synthesis of apoptolidin a. 1. Synthesis of the c(1)-c(11) fragment.
AFFILIATION: Department of Chemistry, Scripps-Florida, Jupiter, Florida 33458, and Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109.
Country: United States
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MEDLINETA: J Org Chem
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