Structural factors influencing linear M-H-M bonding in bis(dialkylphosphino)methane complexes of nickel.

Structural factors influencing linear M-H-M bonding in bis(dialkylphosphino)methane complexes of nickel. Research Abstract Details 

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Structural factors influencing linear M-H-M bonding in bis(dialkylphosphino)methane complexes of nickel. Abstract Text:

William S Tyree,David A Vicic,Paula M B Piccoli,Arthur J Schultz,

Structural data for four closely related dinuclear nickel hydride complexes have been compared in order to gain insight into the factors governing the Ni-H-Ni geometries. The derivatives [(dippm)2Ni2X2](mu-H) [dippm = 1,2-bis(diisopropylphosphino)methane] were found to contain a linear Ni-H-Ni bridge, whereas the derivatives [(dcpm)2Ni2X2](mu-H) [dcpm = 1,2-bis(dicyclohexylphosphino)methane] were found to contain a bent Ni-H-Ni bridge. The number of internal and interatomic CH-to-halide contacts of the former were much shorter and more numerous than the latter, suggesting an important role of external forces in bridging hydride geometries.

Structural factors influencing linear M-H-M bonding in bis(dialkylphosphino)methane complexes of nickel. Publishing Authors By Initials

WS Tyree,DA Vicic,PM Piccoli,AJ Schultz,

For similar organic chemicals: organophosphorus compounds research abstracts see: organic chemicals: organophosphorus compounds research

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Structural factors influencing linear M-H-M bonding in bis(dialkylphosphino)methane complexes of nickel. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Inorganic chemistry

VOLUME: 45

Page Numbers: 8853-5

Journal Abbreviation:

ISSN: 0020-1669

DAY: 30

MONTH: Oct

YEAR: 2006

Structural factors influencing linear M-H-M bonding in bis(dialkylphosphino)methane complexes of nickel. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 366543

Structural factors influencing linear M-H-M bonding in bis(dialkylphosphino)methane complexes of nickel. Keywords Mesh Terms:

KEYWORDS: Organophosphorus Compounds

MESH TERMS: chemistry

Chemical & Substance for Abstract: Structural factors influencing linear M-H-M bonding in bis(dialkylphosphino)methane complexes of nickel. Information

Substance Name: Nickel

Registry Number: 7440-02-0

Grant and Affiliation Information for Structural factors influencing linear M-H-M bonding in bis(dialkylphosphino)methane complexes of nickel.

AFFILIATION: Department of Chemistry and Biochemistry, University of Arkansas, Fayetteville, Arkansas 72701, USA.

Country: United States

AGENCY: United States NCRR

GRANT: RR-015569-06

ACRONYM: RR

MEDLINETA: Inorg Chem

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