Structural elucidation of a nickel boryl complex. A recyclable borylation Ni(II) reagent of bromobenzene.

Structural elucidation of a nickel boryl complex. A recyclable borylation Ni(II) reagent of bromobenzene. Research Abstract Details 

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Structural elucidation of a nickel boryl complex. A recyclable borylation Ni(II) reagent of bromobenzene. Abstract Text:

Debashis Adhikari,John C Huffman,Daniel J Mindiola,Debashis Adhikari,John C Huffman,Daniel J Mindiola,

The first nickel complex bearing a boryl moiety, (PNP)Ni[B(catechol)](PNP = N[2-P(CHMe(2))(2)-4-methylphenyl](2)(-)), has been prepared, structurally characterized, and analyzed by DFT; this rare species is shown to be a recyclable reagent for the borylation of bromobenzene, via an unusual cycle, by applying the ingredients catecholborane and NaBH(4).

Structural elucidation of a nickel boryl complex. A recyclable borylation Ni(II) reagent of bromobenzene. Publishing Authors By Initials

D Adhikari,JC Huffman,DJ Mindiola,D Adhikari,JC Huffman,DJ Mindiola,

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Structural elucidation of a nickel boryl complex. A recyclable borylation Ni(II) reagent of bromobenzene. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Chemical communications (Cambridge, England)

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Page Numbers: 4489-91

Journal Abbreviation: Chem. Commun. (Camb.)

ISSN: 1359-7345

DAY: 11

MONTH: 09

YEAR: 2007

Structural elucidation of a nickel boryl complex. A recyclable borylation Ni(II) reagent of bromobenzene. Information

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LANGUAGE: eng

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Grant and Affiliation Information for Structural elucidation of a nickel boryl complex. A recyclable borylation Ni(II) reagent of bromobenzene.

AFFILIATION: Department of Chemistry and Molecular Structure Center, Indiana University, Bloomington, IN 47405, USA.

Country: England

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MEDLINETA: Chem Commun (Camb)

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