Stereoselective Synthesis of (E)- and (Z)-Fluoroalkenylboronates Using 2-Fluoroalkylideneiodonium Ylides Generated from (2-Fluoro-1-alkenyl)iodonium Salts.

Stereoselective Synthesis of (E)- and (Z)-Fluoroalkenylboronates Using 2-Fluoroalkylideneiodonium Ylides Generated from (2-Fluoro-1-alkenyl)iodonium Salts. Research Abstract Details 

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Stereoselective Synthesis of (E)- and (Z)-Fluoroalkenylboronates Using 2-Fluoroalkylideneiodonium Ylides Generated from (2-Fluoro-1-alkenyl)iodonium Salts. Abstract Text:

Tong Guan,Masanori Yoshida,Shoji Hara,Tong Guan,Masanori Yoshida,Shoji Hara,Tong Guan,Masanori Yoshida,Shoji Hara,

(E)- and (Z)-(fluoroalkenyl)boronates were prepared stereospecifically by the reaction of 2-fluoroalkylideneiodonium ylide generated from (E)- or (Z)-(2-fluoroalkenyl)iodonium salts with di(p-fluorophenoxy)alkylboranes, followed by transesterification to pinacol esters. The resulting pinacol esters of (fluoroalkenyl)boranes were used for the stereoselective synthesis of trisubstituted fluoroalkenes by cross-coupling reactions.

Stereoselective Synthesis of (E)- and (Z)-Fluoroalkenylboronates Using 2-Fluoroalkylideneiodonium Ylides Generated from (2-Fluoro-1-alkenyl)iodonium Salts. Publishing Authors By Initials

T Guan,M Yoshida,S Hara,T Guan,M Yoshida,S Hara,T Guan,M Yoshida,S Hara,

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Stereoselective Synthesis of (E)- and (Z)-Fluoroalkenylboronates Using 2-Fluoroalkylideneiodonium Ylides Generated from (2-Fluoro-1-alkenyl)iodonium Salts. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: The Journal of organic chemistry

VOLUME: 72

Page Numbers: 9617-21

Journal Abbreviation: J. Org. Chem.

ISSN: 0022-3263

DAY: 3

MONTH: 11

YEAR: 2007

Stereoselective Synthesis of (E)- and (Z)-Fluoroalkenylboronates Using 2-Fluoroalkylideneiodonium Ylides Generated from (2-Fluoro-1-alkenyl)iodonium Salts. Information

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LANGUAGE: eng

NlmUniqueID: 2985193

Stereoselective Synthesis of (E)- and (Z)-Fluoroalkenylboronates Using 2-Fluoroalkylideneiodonium Ylides Generated from (2-Fluoro-1-alkenyl)iodonium Salts. Keywords Mesh Terms:

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AFFILIATION: Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan.

Country: United States

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MEDLINETA: J Org Chem

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