Stereoselective [2,3]-sigmatropic rearrangements of unstabilized nitrogen ylides.

Stereoselective [2,3]-sigmatropic rearrangements of unstabilized nitrogen ylides. Research Abstract Details 

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Stereoselective [2,3]-sigmatropic rearrangements of unstabilized nitrogen ylides. Abstract Text:

Robert E Gawley,Kwangyul Moon,

The steric course of the [2,3]-rearrangement of several unstabilized nitrogen ylides has been investigated. The reactions proceed cleanly through an anti transition state, affording modest to good yields of a single diastereomer of the product. In two examples containing an N-cinnamyl group, a competing [1,2]-rearrangement affords a minor product.

Stereoselective [2,3]-sigmatropic rearrangements of unstabilized nitrogen ylides. Publishing Authors By Initials

RE Gawley,K Moon,

For similar natural sciences: chemistry: chemistry, organic: isomerism: stereoisomerism research abstracts see: natural sciences: chemistry: chemistry, organic: isomerism: stereoisomerism research

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Stereoselective [2,3]-sigmatropic rearrangements of unstabilized nitrogen ylides. Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: Organic letters

VOLUME: 9

Page Numbers: 3093-6

Journal Abbreviation: Org. Lett.

ISSN: 1523-7060

DAY: 12

MONTH: 07

YEAR: 2007

Stereoselective [2,3]-sigmatropic rearrangements of unstabilized nitrogen ylides. Information

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LANGUAGE: eng

NlmUniqueID: 100890393

Stereoselective [2,3]-sigmatropic rearrangements of unstabilized nitrogen ylides. Keywords Mesh Terms:

KEYWORDS: Stereoisomerism

MESH TERMS: chemistry

Chemical & Substance for Abstract: Stereoselective [2,3]-sigmatropic rearrangements of unstabilized nitrogen ylides. Information

Substance Name: Nitrogen

Registry Number: 7727-37-9

Grant and Affiliation Information for Stereoselective [2,3]-sigmatropic rearrangements of unstabilized nitrogen ylides.

AFFILIATION: Department of Chemistry and Biochemistry, University of Arkansas, Fayetteville, Arkansas 72701, USA. bgawley@uark.edu

Country: United States

AGENCY: United States PHS

GRANT: P20 R15569

ACRONYM: GM

MEDLINETA: Org Lett

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