Spectral, IR and magnetic studies of Mn(II), Co(II), Ni(II) and Cu(II) complexes with pyrrole-2-carboxyaldehyde thiosemicarbazone (L).

Spectral, IR and magnetic studies of Mn(II), Co(II), Ni(II) and Cu(II) complexes with pyrrole-2-carboxyaldehyde thiosemicarbazone (L). Research Abstract Details 

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Spectral, IR and magnetic studies of Mn(II), Co(II), Ni(II) and Cu(II) complexes with pyrrole-2-carboxyaldehyde thiosemicarbazone (L). Abstract Text:

Sulekh Chandra,Anil Kumar,Sulekh Chandra,Anil Kumar,Sulekh Chandra,Anil Kumar,

Mn(II), Co(II), Ni(II) and Cu(II) complexes are synthesized with thiosemicarbazone (L) derived from pyrrole-2-carboxyaldehyde. These complexes are characterized by elemental analysis, molar conductance, magnetic susceptibility measurement, mass, IR, electronic and EPR spectral studies. The molar conductance measurement of the complexes in DMSO indicates that the complexes are non-electrolyte except Co(L)(2)(NO(3))(2) and Ni(L)(2)(NO(3))(2) complexes which are 1:2 electrolyte. All the complexes are of high-spin type. On the basis of spectral studies an octahedral geometry may be assigned for Mn(II), Co(II) and Ni(II) complexes except Co(L)(2)(NO(3))(2) and Ni(L)(2)(NO(3))(2) which are of tetrahedral geometry. A tetragonal geometry may be suggested for Cu(II) complexes.

Spectral, IR and magnetic studies of Mn(II), Co(II), Ni(II) and Cu(II) complexes with pyrrole-2-carboxyaldehyde thiosemicarbazone (L). Publishing Authors By Initials

S Chandra,A Kumar,S Chandra,A Kumar,S Chandra,A Kumar,

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Spectral, IR and magnetic studies of Mn(II), Co(II), Ni(II) and Cu(II) complexes with pyrrole-2-carboxyaldehyde thiosemicarbazone (L). Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Spectrochimica acta. Part A, Molecular and biomole

VOLUME: 68

Page Numbers: 469-73

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ISSN: 1386-1425

DAY: 15

MONTH: 12

YEAR: 2006

Spectral, IR and magnetic studies of Mn(II), Co(II), Ni(II) and Cu(II) complexes with pyrrole-2-carboxyaldehyde thiosemicarbazone (L). Information

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LANGUAGE: eng

NlmUniqueID: 9602533

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AFFILIATION: Department of Chemistry, Zakir Husain College, J.L.N. Marg, New Delhi 110002, India.

Country: England

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MEDLINETA: Spectrochim Acta A Mol Biomol

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