Second Virial Coefficient of bmimBF(4)/Triton X-100/ Cyclohexane Ionic Liquid Microemulsion as Investigated by Microcalorimetry.

Second Virial Coefficient of bmimBF(4)/Triton X-100/ Cyclohexane Ionic Liquid Microemulsion as Investigated by Microcalorimetry. Research Abstract Details 

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Second Virial Coefficient of bmimBF(4)/Triton X-100/ Cyclohexane Ionic Liquid Microemulsion as Investigated by Microcalorimetry. Abstract Text:

Na Li,Shaohua Zhang,Liqiang Zheng,Yan'an Gao,Li Yu,

The second virial coefficient of the ionic liquid (IL) microemulsion was obtained for the first time using microcalorimetry. The heat of dilution of the microemulsion solutions was measured by isothermal titration microcalorimetry (ITC), and the second virial coefficient was derived from the heat of dilution and the number density of the IL microemulsion solutions on the basis of a hard-sphere interaction potential assumption and as a function of the second-order polynomial. The validity of the second virial coefficient was confirmed by the percolation behavior of different ionic liquid microemulsion solutions of Triton X-100 in cyclohexane with or without added salts. The information obtained from the second virial coefficient shows that the interactions between ionic liquid microemulsion droplets are much stronger than those for traditional microemulsions, which may be attributed to the relatively larger size of the microemulsion droplets.

Second Virial Coefficient of bmimBF(4)/Triton X-100/ Cyclohexane Ionic Liquid Microemulsion as Investigated by Microcalorimetry. Publishing Authors By Initials

N Li,S Zhang,L Zheng,Y Gao,L Yu,

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Second Virial Coefficient of bmimBF(4)/Triton X-100/ Cyclohexane Ionic Liquid Microemulsion as Investigated by Microcalorimetry. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Langmuir : the ACS journal of surfaces and colloid

VOLUME: 24

Page Numbers: 2973-6

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ISSN: 0743-7463

DAY: 1

MONTH: 03

YEAR: 2008

Second Virial Coefficient of bmimBF(4)/Triton X-100/ Cyclohexane Ionic Liquid Microemulsion as Investigated by Microcalorimetry. Information

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LANGUAGE: eng

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AFFILIATION: Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education, Jinan 250100, China.

Country: United States

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MEDLINETA: Langmuir

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