Ruthenium-catalyzed mild C-H oxyfunctionalization of cyclic steroidal ethers.

Ruthenium-catalyzed mild C-H oxyfunctionalization of cyclic steroidal ethers. Research Abstract Details 

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Ruthenium-catalyzed mild C-H oxyfunctionalization of cyclic steroidal ethers. Abstract Text:

Jong Seok Lee,Hui Cao,Philip L Fuchs,

Ruthenium-catalyzed site-specific C-H oxyfunctionalization of steroidal ethers with periodate or bromate as terminal oxidants in phosphate buffer provided the acid-sensitive C-16 hydroxy compounds in high yields. Phosphate buffer (pH 7.5) significantly inhibits formation of unwanted side products generated under more acidic reaction conditions. A key example is demonstrated at the 100 g scale.

Ruthenium-catalyzed mild C-H oxyfunctionalization of cyclic steroidal ethers. Publishing Authors By Initials

JS Lee,H Cao,PL Fuchs,

For similar polycyclic compounds: steroids research abstracts see: polycyclic compounds: steroids research

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Ruthenium-catalyzed mild C-H oxyfunctionalization of cyclic steroidal ethers. Journal Published:

PUBLICATION TYPE: Research Support, N.I.H., Extr

Journal: The Journal of organic chemistry

VOLUME: 72

Page Numbers: 5820-3

Journal Abbreviation: J. Org. Chem.

ISSN: 0022-3263

DAY: 23

MONTH: 06

YEAR: 2007

Ruthenium-catalyzed mild C-H oxyfunctionalization of cyclic steroidal ethers. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 2985193

Ruthenium-catalyzed mild C-H oxyfunctionalization of cyclic steroidal ethers. Keywords Mesh Terms:

KEYWORDS: Steroids

MESH TERMS: chemistry

Chemical & Substance for Abstract: Ruthenium-catalyzed mild C-H oxyfunctionalization of cyclic steroidal ethers. Information

Substance Name: Ruthenium

Registry Number: 7440-18-8

Grant and Affiliation Information for Ruthenium-catalyzed mild C-H oxyfunctionalization of cyclic steroidal ethers.

AFFILIATION: Department of Chemistry, Purdue University, West Lafayette, IN 47907, USA.

Country: United States

AGENCY: United States NCI

GRANT: CA 60548

ACRONYM: CA

MEDLINETA: J Org Chem

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