Room-temperature ionic liquids: slow dynamics, viscosity, and the red edge effect.

Room-temperature ionic liquids: slow dynamics, viscosity, and the red edge effect. Research Abstract Details 

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Room-temperature ionic liquids: slow dynamics, viscosity, and the red edge effect. Abstract Text:

Zhonghan Hu,Claudio J Margulis,Zhonghan Hu,Claudio J Margulis,Zhonghan Hu,Claudio J Margulis,

Ionic liquids (ILs) have recently attracted significant attention from academic and industrial sources. This is because, while their vapor pressures are negligible, many of them are liquids at room temperature and can dissolve a wide range of polar and nonpolar organic and inorganic molecules. In this Account, we discuss the progress of our laboratory in understanding the dynamics, spectroscopy, and fluid dynamics of selected imidazolium-based ILs using computational and analytical tools that we have recently developed. Our results indicate that the red edge effect, the non-Newtonian behavior, and the existence of locally heterogeneous environments on a time scale relevant to chemical and photochemical reactivity are closely linked to the viscosity and highly structured character of these liquids.

Room-temperature ionic liquids: slow dynamics, viscosity, and the red edge effect. Publishing Authors By Initials

Z Hu,CJ Margulis,Z Hu,CJ Margulis,Z Hu,CJ Margulis,

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Room-temperature ionic liquids: slow dynamics, viscosity, and the red edge effect. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Accounts of chemical research

VOLUME: 40

Page Numbers: 1097-105

Journal Abbreviation: Acc. Chem. Res.

ISSN: 0001-4842

DAY: 28

MONTH: 07

YEAR: 2007

Room-temperature ionic liquids: slow dynamics, viscosity, and the red edge effect. Information

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LANGUAGE: eng

NlmUniqueID: 157313

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AFFILIATION: claudio-margulis@uiowa.edu.

Country: United States

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MEDLINETA: Acc Chem Res

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