Reversible redox behavior between stannole dianion and bistannole-1,2-dianion.

Reversible redox behavior between stannole dianion and bistannole-1,2-dianion. Research Abstract Details 

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Reversible redox behavior between stannole dianion and bistannole-1,2-dianion. Abstract Text:

Ryuta Haga,Masaichi Saito,Michikazu Yoshioka,

The reversible redox behavior between the stannole dianion and the bistannole-1,2-dianion is demonstrated. Reaction of the stannole dianion with oxygen (1 eq) gives the 1,2-bistannole-1,2-dianion which is a tin-analogue of the cyclopentadienyl anion in 94% yield. Reaction of the stannole dianion with ferrocenium tetrafluoroborate (1 eq) also gives the 1,2-dianion. The 1,2-bistannole-1,2-dianion has a nonaromatic nature as evidenced by X-ray and NMR analysis. Reduction of the 1,2-dianion with lithium gives the starting dianion.

Reversible redox behavior between stannole dianion and bistannole-1,2-dianion. Publishing Authors By Initials

R Haga,M Saito,M Yoshioka,

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Reversible redox behavior between stannole dianion and bistannole-1,2-dianion. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 128

Page Numbers: 4934-5

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 19

MONTH: Apr

YEAR: 2006

Reversible redox behavior between stannole dianion and bistannole-1,2-dianion. Information

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LANGUAGE: eng

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Grant and Affiliation Information for Reversible redox behavior between stannole dianion and bistannole-1,2-dianion.

AFFILIATION: Department of Chemistry, Faculty of Science, Saitama University, Shimo-okubo, Sakura-ku, Saitama-city, Saitama 338-8570 Japan.

Country: United States

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MEDLINETA: J Am Chem Soc

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