Reversible O-O bond cleavage and formation of a peroxo moiety of a peroxocarbonate ligand mediated by an iron(III) complex.

Reversible O-O bond cleavage and formation of a peroxo moiety of a peroxocarbonate ligand mediated by an iron(III) complex. Research Abstract Details 

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Reversible O-O bond cleavage and formation of a peroxo moiety of a peroxocarbonate ligand mediated by an iron(III) complex. Abstract Text:

Hideki Furutachi,Koji Hashimoto,Shigenori Nagatomo,Taichi Endo,Shuhei Fujinami,Yoshihito Watanabe,Teizo Kitagawa,Masatatsu Suzuki,

A mononuclear iron(III) complex containing a peroxocarbonate ligand, [Fe(qn)2(O2C(O)O)]- (qn = quinaldinate), underwent the reversible O-O bond cleavage and reformation of the peroxo group via the formation of FeIV=O or FeV=O species, which was confirmed by the resonance Raman and ESI-TOF/MS measurements.

Reversible O-O bond cleavage and formation of a peroxo moiety of a peroxocarbonate ligand mediated by an iron(III) complex. Publishing Authors By Initials

H Furutachi,K Hashimoto,S Nagatomo,T Endo,S Fujinami,Y Watanabe,T Kitagawa,M Suzuki,

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Reversible O-O bond cleavage and formation of a peroxo moiety of a peroxocarbonate ligand mediated by an iron(III) complex. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 127

Page Numbers: 4550-1

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 6

MONTH: Apr

YEAR: 2005

Reversible O-O bond cleavage and formation of a peroxo moiety of a peroxocarbonate ligand mediated by an iron(III) complex. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

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Grant and Affiliation Information for Reversible O-O bond cleavage and formation of a peroxo moiety of a peroxocarbonate ligand mediated by an iron(III) complex.

AFFILIATION: Department of Chemistry, Faculty of Science, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.

Country: United States

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MEDLINETA: J Am Chem Soc

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