Rapid vapor-phase fabrication of organic-inorganic hybrid superlattices with monolayer precision.

Rapid vapor-phase fabrication of organic-inorganic hybrid superlattices with monolayer precision. Research Abstract Details 

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Rapid vapor-phase fabrication of organic-inorganic hybrid superlattices with monolayer precision. Abstract Text:

Byoung H Lee,Min Ki Ryu,Sung-Yool Choi,Kwang-H Lee,Seongil Im,Myung M Sung,Byoung H Lee,Min Ki Ryu,Sung-Yool Choi,Kwang-H Lee,Seongil Im,Myung M Sung,Byoung H Lee,Min Ki Ryu,Sung-Yool Choi,Kwang-H Lee,Seongil Im,Myung M Sung,

We report a new layer-by-layer growth method of self-assembled organic multilayer thin films based on gas-phase reactions. In the present molecular layer deposition (MLD) process, alkylsiloxane self-assembled multilayers (SAMs) were grown under vacuum by repeated sequential adsorptions of C=C-terminated alkylsilane and titanium hydroxide. The MLD method is a self- limiting layer-by-layer growth process, and is perfectly compatible with the atomic layer deposition (ALD) method. The SAMs films prepared exhibited good thermal and mechanical stability, and various unique electrical properties. The MLD method, combined with ALD, was applied to the preparation of organic-inorganic hybrid nanolaminate films in the ALD chamber. The organic-inorganic hybrid superlattices were then used as active mediums for two-terminal electrical bistable devices. The advantages of the MLD method with ALD include accurate control of film thickness, large-scale uniformity, highly conformal layering, sharp interfaces, and a vast library of possible materials. The MLD method with ALD is an ideal fabrication technique for various organic-inorganic hybrid superlattices.

Rapid vapor-phase fabrication of organic-inorganic hybrid superlattices with monolayer precision. Publishing Authors By Initials

BH Lee,MK Ryu,SY Choi,KH Lee,S Im,MM Sung,BH Lee,MK Ryu,SY Choi,KH Lee,S Im,MM Sung,BH Lee,MK Ryu,SY Choi,KH Lee,S Im,MM Sung,

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Rapid vapor-phase fabrication of organic-inorganic hybrid superlattices with monolayer precision. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 129

Page Numbers: 16034-41

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 1520-5126

DAY: 30

MONTH: 11

YEAR: 2007

Rapid vapor-phase fabrication of organic-inorganic hybrid superlattices with monolayer precision. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

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AFFILIATION: Contribution from the Department of Chemistry, Hanyang University, Seoul 133-791, Korea, Nanoelectronic Devices Team, ETRI, Daejeon 305-700, Korea, and Institute of Physics and Applied Physics, Yonsei University, Seoul 120-749, Korea.

Country: United States

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MEDLINETA: J Am Chem Soc

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