Radially Diblock Nanotube: Site-Selective Functionalization of a Tubularly Assembled Hexabenzocoronene.

Radially Diblock Nanotube: Site-Selective Functionalization of a Tubularly Assembled Hexabenzocoronene. Research Abstract Details 

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Radially Diblock Nanotube: Site-Selective Functionalization of a Tubularly Assembled Hexabenzocoronene. Abstract Text:

Justin L Mynar,Takuya Yamamoto,Atsuko Kosaka,Takanori Fukushima,Noriyuki Ishii,Takuzo Aida,Justin L Mynar,Takuya Yamamoto,Atsuko Kosaka,Takanori Fukushima,Noriyuki Ishii,Takuzo Aida,

An amphiphilic Gemini-shaped hexa-peri-hexabenzocoronene (1) with azide functionalities self-assembles to form graphitic nanotubes whose interior and exterior surfaces can be post-functionalized by "click chemistry". A click reaction of the nanotubes with bulky macromolecules such as a dendronized alkyne (G2-alkyne) takes place site-selectively on the exterior surface of the nanotubes, leaving the azide functionalities on the interior surface mostly intact. A subsequent click reaction of the resulting nanotubes with alkynes having a much smaller steric bulk allows the remaining azide groups to be functionalized, affording radially diblock graphitic nanotubes.

Radially Diblock Nanotube: Site-Selective Functionalization of a Tubularly Assembled Hexabenzocoronene. Publishing Authors By Initials

JL Mynar,T Yamamoto,A Kosaka,T Fukushima,N Ishii,T Aida,JL Mynar,T Yamamoto,A Kosaka,T Fukushima,N Ishii,T Aida,

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Radially Diblock Nanotube: Site-Selective Functionalization of a Tubularly Assembled Hexabenzocoronene. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 130

Page Numbers: 1530-1

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 1520-5126

DAY: 11

MONTH: 01

YEAR: 2008

Radially Diblock Nanotube: Site-Selective Functionalization of a Tubularly Assembled Hexabenzocoronene. Information

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LANGUAGE: eng

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AFFILIATION: ERATO-SORST Nanospace Project, Japan Science and Technology Agency (JST), National Museum of Emerging Science and Innovation, 2-41 Aomi, Koto-ku, Tokyo 135-0064, Japan.

Country: United States

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MEDLINETA: J Am Chem Soc

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