[Structure: see text] OH...OH hydrogen bond mediated scalar couplings have been observed in acyclic syn- and anti-1,3-diols using a 2D 1H COSYLR NMR experiment and quantified with an uncertainty of +/-0.02 Hz with a selective-excitation spin-echo NMR experiment. A theoretical investigation confirmed the importance of the hydrogen bond in mediating the spin-spin coupling in these systems.
Qualitative and quantitative measurements of hydrogen bond mediated scalar couplings in acyclic 1,3-diols. Publishing Authors By Initials
Qualitative and quantitative measurements of hydrogen bond mediated scalar couplings in acyclic 1,3-diols. Journal Published:
PUBLICATION TYPE: Research Support, U.S. Gov't,
Journal: Organic letters
VOLUME: 8
Page Numbers: 5321-3
Journal Abbreviation: Org. Lett.
ISSN: 1523-7060
DAY: 9
MONTH: Nov
YEAR: 2006
Qualitative and quantitative measurements of hydrogen bond mediated scalar couplings in acyclic 1,3-diols. Information
Number of References:
LANGUAGE: eng
NlmUniqueID: 100890393
Qualitative and quantitative measurements of hydrogen bond mediated scalar couplings in acyclic 1,3-diols. Keywords Mesh Terms:
KEYWORDS: Molecular Structure
MESH TERMS: chemistry
Chemical & Substance for Abstract: Qualitative and quantitative measurements of hydrogen bond mediated scalar couplings in acyclic 1,3-diols. Information
Substance Name: Hydrocarbons, Acyclic
Registry Number: 0
Grant and Affiliation Information for Qualitative and quantitative measurements of hydrogen bond mediated scalar couplings in acyclic 1,3-diols.
AFFILIATION: Department of Chemistry, Lewis and Clark College, 0615 SW Palatine Hill Road, Portland, Oregon 97219, USA.
Country: United States
AGENCY: United States NIGMS
GRANT: GM-43854
ACRONYM: GM
MEDLINETA: Org Lett
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