PtCl2-catalyzed cycloisomerizations of 5-en-1-yn-3-ol systems.

PtCl2-catalyzed cycloisomerizations of 5-en-1-yn-3-ol systems. Research Abstract Details 

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PtCl2-catalyzed cycloisomerizations of 5-en-1-yn-3-ol systems. Abstract Text:

Youssef Harrak,Christophe Blaszykowski,Matthieu Bernard,Kevin Cariou,Emily Mainetti,Virginie ,Anne-Lise Dhimane,Louis Fensterbank,Max Malacria,

5-En-1-yn-3-ol substrates bearing a free hydroxyl group or an acyl group are highly versatile partners for PtCl2-catalyzed cycloisomerizations. Electrophilic activation of the alkyne moiety triggers at wish a hydride or an O-acyl migration yielding at the end to regioisomeric keto derivatives. The efficient preparation of Sabina ketone, an important monoterpene precursor, has been worked out.

PtCl2-catalyzed cycloisomerizations of 5-en-1-yn-3-ol systems. Publishing Authors By Initials

Y Harrak,C Blaszykowski,M Bernard,K Cariou,E Mainetti,V ,AL Dhimane,L Fensterbank,M Malacria,

For similar inorganic chemicals: platinum compounds research abstracts see: inorganic chemicals: platinum compounds research

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PtCl2-catalyzed cycloisomerizations of 5-en-1-yn-3-ol systems. Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: Journal of the American Chemical Society

VOLUME: 126

Page Numbers: 8656-7

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 21

MONTH: Jul

YEAR: 2004

PtCl2-catalyzed cycloisomerizations of 5-en-1-yn-3-ol systems. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

PtCl2-catalyzed cycloisomerizations of 5-en-1-yn-3-ol systems. Keywords Mesh Terms:

KEYWORDS: Platinum Compounds

MESH TERMS: chemistry

Chemical & Substance for Abstract: PtCl2-catalyzed cycloisomerizations of 5-en-1-yn-3-ol systems. Information

Substance Name: platinum chloride

Registry Number: 12648-47-4

Grant and Affiliation Information for PtCl2-catalyzed cycloisomerizations of 5-en-1-yn-3-ol systems.

AFFILIATION: Université Pierre et Marie Curie, Laboratoire de Chimie Organique, UMR CNRS 7611, Tour 44-54, case 229, 4, place Jussieu, 75252 Paris 05, France.

Country: United States

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MEDLINETA: J Am Chem Soc

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