Preorganization in highly enantioselective diaza-Cope rearrangement reaction.

Preorganization in highly enantioselective diaza-Cope rearrangement reaction. Research Abstract Details 

Research Abstract Table of Contents

Jump to the:

Preorganization in highly enantioselective diaza-Cope rearrangement reaction. Abstract Text:

Hae-Jo Kim,Hyunwoo Kim,Gamil Alhakimi,Eui June Jeong,Nirusha Thavarajah,Lisa Studnicki,Alicja Koprianiuk,Alan J Lough,Junghun Suh,Jik Chin,

Crystal structure and activation entropy data indicate that H-bond directed diaza-Cope rearrangement of chiral diimines takes place with a high degree of preorganization. CD spectroscopy and HPLC data show that there is inversion of stereochemistry for the reaction with excellent enantioselectivity.

Preorganization in highly enantioselective diaza-Cope rearrangement reaction. Publishing Authors By Initials

HJ Kim,H Kim,G Alhakimi,EJ Jeong,N Thavarajah,L Studnicki,A Koprianiuk,AJ Lough,J Suh,J Chin,

For similar abstracts research abstracts see: abstracts research

PUBMED ID PMID:

MEDLINE DATE:

Preorganization in highly enantioselective diaza-Cope rearrangement reaction. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 127

Page Numbers: 16370-1

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 30

MONTH: Nov

YEAR: 2005

Preorganization in highly enantioselective diaza-Cope rearrangement reaction. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 7503056

Preorganization in highly enantioselective diaza-Cope rearrangement reaction. Keywords Mesh Terms:

KEYWORDS:

MESH TERMS:

Chemical & Substance for Abstract: Preorganization in highly enantioselective diaza-Cope rearrangement reaction. Information

Substance Name:

Registry Number:

Grant and Affiliation Information for Preorganization in highly enantioselective diaza-Cope rearrangement reaction.

AFFILIATION: Department of Chemistry, University of Toronto, 80 St. George Street, Toronto M5S 3H6, Canada.

Country: United States

AGENCY:

GRANT:

ACRONYM:

MEDLINETA: J Am Chem Soc

REFSOURCE:

DATABASENAME:

ACCESSION NUMBER:

Number Hits: 0

Preorganization in highly enantioselective diaza-Cope rearrangement reaction Related Publications

• A comparison of DNA copy number profiling platforms.
• Acetylation-dependent signal transduction for type I interferon receptor.
• Altered partition of serum cholesterol and cholesteryl ester in a petroleum ether-ethanol-water system after incubation.
• CHF1/Hey2 plays a pivotal role in left ventricular maturation through suppression of ectopic atrial gene expression.
• Cell therapy in murine atherosclerosis: in vivo imaging with high-resolution helical SPECT.
• Continuing benefit of zoledronic acid in preventing skeletal complications in patients with bone metastases.
• Do religious physicians disproportionately care for the underserved?
• Evaluation of lipid oxidation and oxidative products as affected by pork meat cut, packaging method, and storage time during frozen storage (-10 degrees C).
• Evolution and termination of a femtosecond laser filament in air.
• Following the call: how providers make sense of their decisions to work in faith-based and secular urban community health centers.
• Genome-wide mapping of RELA(p65) binding identifies E2F1 as a transcriptional activator recruited by NF-kappaB upon TLR4 activation.
• Laryngeal nerve monitoring and minimally invasive thyroid surgery: complementary technologies.
• Logistic regression for disease classification using microarray data: model selection in a large p and small n case.
• Obstetric cholestasis in Hong Kong--local experience with eight consecutive cases.
• Parkin-mediated K63-linked polyubiquitination targets misfolded DJ-1 to aggresomes via binding to HDAC6.
• Performance and characteristics of an IR localizing system for radiation therapy.
• Phage immobilized magnetoelastic sensor for the detection of Salmonella typhimurium.
• Predictors of patient selection in bariatric surgery.
• Preparation and properties of electrophoretic microcapsules for electronic paper.
• Provider perceptions of limited health literacy in community health centers.
• Realization of complex onsets by pediatric users of cochlear implants.
• Reprogramming the amino-acid substrate specificity of orthogonal aminoacyl-tRNA synthetases to expand the genetic code of eukaryotic cells.
• Robotics and its applications in stereotactic radiosurgery.
• Scenario of a dirty bomb in an urban environment and acute management of radiation poisoning and injuries.
• Selective enrichment of DJ-1 protein in primate striatal neuronal processes: implications for Parkinson's disease.
• The cost-effectiveness of improving diabetes care in u.s. Federally qualified community health centers.
• Transcription factor CHF1/Hey2 regulates the global transcriptional response to platelet-derived growth factor in vascular smooth muscle cells.
• Trust and reciprocity: foundational principles for human subjects imaging research.
• Two cases of postmaturity-related perinatal mortality in non-local expectant mothers.
• Variation in consonant cluster production by pediatric cochlear implant users.