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Preconcentration of trace arsenite and arsenate with titanium dioxide nanoparticles and subsequent determination by silver diethyldithiocarbamate spectrophotometric method.

Preconcentration of trace arsenite and arsenate with titanium dioxide nanoparticles and subsequent determination by silver diethyldithiocarbamate spectrophotometric method. Research Abstract Details 

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  • Preconcentration of trace arsenite and arsenate with titanium dioxide nanoparticles and subsequent determination by silver diethyldithiocarbamate spectrophotometric method. Abstract Text:

    yabing xiaoYabing Xiao,jie lingJie Ling,shahua qianShahua Qian,anqing linAnqing Lin,wenjie zhengWenjie Zheng,weiya xuWeiya Xu,yuxuan luoYuxuan Luo,man zhangMan Zhang,yabing xiaoYabing Xiao,jie lingJie Ling,shahua qianShahua Qian,anqing linAnqing Lin,wenjie zhengWenjie Zheng,weiya xuWeiya Xu,yuxuan luoYuxuan Luo,man zhangMan Zhang,

    A novel method of preconcentration of trace arsenite and arsenate by using titanium dioxide nanoparticles as adsorbent was described. The concentrations of preconcentrated arsenite and arsenate were determined by a silver diethyldithiocarbamate spectrophotometric method without desorption. Batch adsorption experiments were carried out as a function of the pH, contact time, amount of titanium dioxide nanoparticles, and solution volume. In the pH range 5 to 6, adsorption rates of arsenite and arsenate were higher than 98%. The calibration coefficient was 0.9991, and the linear range was 0 to 100 microg/L. The developed method was precise, with the relative standard deviation <5% at concentration level of 10 microg/L, with a detection limit (3sigma, n=6) of 0.44 microg/L. The accuracy of the method for total arsenic was validated by standard reference materials (SRM 3103a) (National Institute of Standards and Technology, Gaithersburg, Maryland). The method was also applied to the analysis of arsenite and arsenate in natural water samples to verify the accuracy. The recovery values remained in a narrow range, from 95 to 103%.

    Preconcentration of trace arsenite and arsenate with titanium dioxide nanoparticles and subsequent determination by silver diethyldithiocarbamate spectrophotometric method. Publishing Authors By Initials

    y xiaoY Xiao,j lingJ Ling,s qianS Qian,a linA Lin,w zhengW Zheng,w xuW Xu,y luoY Luo,m zhangM Zhang,y xiaoY Xiao,j lingJ Ling,s qianS Qian,a linA Lin,w zhengW Zheng,w xuW Xu,y luoY Luo,m zhangM Zhang,

    For similar abstracts research abstracts see: abstracts research

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    Preconcentration of trace arsenite and arsenate with titanium dioxide nanoparticles and subsequent determination by silver diethyldithiocarbamate spectrophotometric method. Journal Published:

    PUBLICATION TYPE: Journal Article

    Journal: Water environment research : a research publicatio

    VOLUME: 79

    Page Numbers: 1015-22

    Journal Abbreviation: Water Environ. Res.

    ISSN: 1061-4303

    DAY: 3

    MONTH: Sep

    YEAR: 2007

    Preconcentration of trace arsenite and arsenate with titanium dioxide nanoparticles and subsequent determination by silver diethyldithiocarbamate spectrophotometric method. Information

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    LANGUAGE: eng

    NlmUniqueID: 9886167

    Preconcentration of trace arsenite and arsenate with titanium dioxide nanoparticles and subsequent determination by silver diethyldithiocarbamate spectrophotometric method. Keywords Mesh Terms:

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    Grant and Affiliation Information for Preconcentration of trace arsenite and arsenate with titanium dioxide nanoparticles and subsequent determination by silver diethyldithiocarbamate spectrophotometric method.

    AFFILIATION: Tianjin Enter-Exit Inspection and Quarantine Bureau, Tianjin, China.

    Country: United States

    United States Research PublicationUnited States Research Publication

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    MEDLINETA: Water Environ Res

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