PN Bond Formation via Incomplete N-Atom Transfer from a Ferrous Amide Precursor.

PN Bond Formation via Incomplete N-Atom Transfer from a Ferrous Amide Precursor. Research Abstract Details 

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PN Bond Formation via Incomplete N-Atom Transfer from a Ferrous Amide Precursor. Abstract Text:

Incomplete N-atom transfer from Fe to P is observed when the ferrous amide complex (PNP)Fe(dbabh) (PNP (-) = N[2-P( ( i )Pr) 2-4-methylphenyl] 2, dbabh = 2,3:5,6-dibenzo-7-azabicyclo[2.2.1]hepta-2,5-diene), prepared from salt metathesis of (PNP)FeCl and Li(dbabh), is thermolyzed at 70 degrees C over 48 h in C 6D 6. Several plausible reaction pathways resulting from the transformation of (PNP)Fe(dbabh) are discussed, including the possibility of an Fe(IV) nitride as an intermediate.

PN Bond Formation via Incomplete N-Atom Transfer from a Ferrous Amide Precursor. Publishing Authors By Initials

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PN Bond Formation via Incomplete N-Atom Transfer from a Ferrous Amide Precursor. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Inorganic chemistry

VOLUME: 47

Page Numbers: 4439-41

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ISSN: 0020-1669

DAY: 8

MONTH: 05

YEAR: 2008

PN Bond Formation via Incomplete N-Atom Transfer from a Ferrous Amide Precursor. Information

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LANGUAGE: eng

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AFFILIATION: mindiola@indiana.edu.

Country: United States

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MEDLINETA: Inorg Chem

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