Platinum-catalyzed intramolecular hydroamination of unactivated olefins with secondary alkylamines.

Platinum-catalyzed intramolecular hydroamination of unactivated olefins with secondary alkylamines. Research Abstract Details 

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Platinum-catalyzed intramolecular hydroamination of unactivated olefins with secondary alkylamines. Abstract Text:

Christopher F Bender,Ross A Widenhoefer,

Reaction of benzyl-2,2-diphenyl-4-pentenylamine with a catalytic 1:2 mixture of [PtCl2(H2C=CH2)]2 (2.5 mol %) and PPh3 in dioxane at 120 degrees C for 16 h led to isolation of 1-benzyl-2-methyl-4,4-diphenylpyrrolidine in 75% yield. A number of gamma- and delta-amino olefins underwent intramolecular hydroamination to form the corresponding pyrrolidine derivatives in moderate to good yield. The reaction displayed excellent functional group compatibility and low moisture sensitivity.

Platinum-catalyzed intramolecular hydroamination of unactivated olefins with secondary alkylamines. Publishing Authors By Initials

CF Bender,RA Widenhoefer,

For similar organic chemicals: organometallic compounds: organoplatinum compounds research abstracts see: organic chemicals: organometallic compounds: organoplatinum compounds research

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Platinum-catalyzed intramolecular hydroamination of unactivated olefins with secondary alkylamines. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Journal of the American Chemical Society

VOLUME: 127

Page Numbers: 1070-1

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 2

MONTH: Feb

YEAR: 2005

Platinum-catalyzed intramolecular hydroamination of unactivated olefins with secondary alkylamines. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

Platinum-catalyzed intramolecular hydroamination of unactivated olefins with secondary alkylamines. Keywords Mesh Terms:

KEYWORDS: Organoplatinum Compounds

MESH TERMS: chemistry

Chemical & Substance for Abstract: Platinum-catalyzed intramolecular hydroamination of unactivated olefins with secondary alkylamines. Information

Substance Name: Organoplatinum Compounds

Registry Number: 0

Grant and Affiliation Information for Platinum-catalyzed intramolecular hydroamination of unactivated olefins with secondary alkylamines.

AFFILIATION: P M Gross Chemical Laboratory, Duke University, Durham, North Carolina 27708-0346, USA.

Country: United States

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MEDLINETA: J Am Chem Soc

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