Place exchange reactions of alkyl thiols on gold nanoparticles.

Place exchange reactions of alkyl thiols on gold nanoparticles. Research Abstract Details 

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Place exchange reactions of alkyl thiols on gold nanoparticles. Abstract Text:

Adil Kassam,Glen Bremner,Brad Clark,Gerardo Ulibarri,R Bruce Lennox,

The kinetics and equilibrium position of place exchange (alkylthiol-for-alkylthiol) reactions of gold nanoparticles are reported. These reactions were monitored via a gas chromatography analysis of structurally similar incoming and outgoing alkylthiols, as a function of time. The place exchange reactions described here proceed to an equilibrium position, where Keq approximately 1. The product-time data follow Langmuir diffusion kinetics.

Place exchange reactions of alkyl thiols on gold nanoparticles. Publishing Authors By Initials

A Kassam,G Bremner,B Clark,G Ulibarri,RB Lennox,

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Place exchange reactions of alkyl thiols on gold nanoparticles. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 128

Page Numbers: 3476-7

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 22

MONTH: Mar

YEAR: 2006

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LANGUAGE: eng

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Grant and Affiliation Information for Place exchange reactions of alkyl thiols on gold nanoparticles.

AFFILIATION: Department of Chemistry and Centre for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Street W, Montreal, QC H3A 2K6, Canada.

Country: United States

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MEDLINETA: J Am Chem Soc

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