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Photo-induced proton-transfer cycle of 2-naphthol in faujasite zeolitic nanocavities.

Photo-induced proton-transfer cycle of 2-naphthol in faujasite zeolitic nanocavities. Research Abstract Details 

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  • Photo-induced proton-transfer cycle of 2-naphthol in faujasite zeolitic nanocavities. Abstract Text:

    young-shin leeYoung-Shin Lee,hyunung yuHyunung Yu,oh-hoon kwonOh-Hoon Kwon,du-jeon jangDu-Jeon Jang,young-shin leeYoung-Shin Lee,hyunung yuHyunung Yu,oh-hoon kwonOh-Hoon Kwon,du-jeon jangDu-Jeon Jang,

    The excited-state deprotonation and ground-state reprotonation of a 2-naphthol molecule encapsulated in the zeolitic nanocavity of NaX have been studied by measuring static and time-resolved spectra of fluorescence and reflectance. The excited molecule undergoes enol dissociation within 300 ps to form an isolated ion pair, which undergoes geminate recombination in 1200 ps or separation to produce the anionic species of 2-naphtholate on the time scale of 2500 ps. Ground-state reprotonation, controlled by the diffusion rate of a proton, is then followed in 0.8 ms with an activation energy of 13 kJ mol(-1).

    Photo-induced proton-transfer cycle of 2-naphthol in faujasite zeolitic nanocavities. Publishing Authors By Initials

    ys leeYS Lee,h yuH Yu,oh kwonOH Kwon,dj jangDJ Jang,ys leeYS Lee,h yuH Yu,oh kwonOH Kwon,dj jangDJ Jang,

    For similar abstracts research abstracts see: abstracts research

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    Photo-induced proton-transfer cycle of 2-naphthol in faujasite zeolitic nanocavities. Journal Published:

    PUBLICATION TYPE: Journal Article

    Journal: Physical chemistry chemical physics : PCCP

    VOLUME: 10

    Page Numbers: 153-8

    Journal Abbreviation:

    ISSN: 1463-9076

    DAY: 24

    MONTH: 10

    YEAR: 2007

    Photo-induced proton-transfer cycle of 2-naphthol in faujasite zeolitic nanocavities. Information

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    LANGUAGE: eng

    NlmUniqueID: 100888160

    Photo-induced proton-transfer cycle of 2-naphthol in faujasite zeolitic nanocavities. Keywords Mesh Terms:

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    Grant and Affiliation Information for Photo-induced proton-transfer cycle of 2-naphthol in faujasite zeolitic nanocavities.

    AFFILIATION: School of Chemistry and Centre for Space-Time Molecular Dynamics, Seoul National University, NS60, Seoul, 151-742, Korea.

    Country: England

    England Research PublicationEngland Research Publication

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    MEDLINETA: Phys Chem Chem Phys

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