Phosphorescent excited state of [Au2[(Ph2Sb)2O]3]2+: Jahn-Teller distortion at only one gold(I) center.

Phosphorescent excited state of [Au2[(Ph2Sb)2O]3]2+: Jahn-Teller distortion at only one gold(I) center. Research Abstract Details 

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Phosphorescent excited state of [Au2[(Ph2Sb)2O]3]2+: Jahn-Teller distortion at only one gold(I) center. Abstract Text:

Vilma R Bojan,Eduardo J ,Antonio Laguna, ,Miguel Monge,M Elena Olmos,Cristian Silvestru,

Dinuclear three-coordinate Au(I) complex [Au2{(Ph2Sb)2O}3](ClO4)2 1 displays an interesting phosphorescent behavior in which a large Stokes' shift is observed. Ab initio calculations show that the main distortion for the first triplet excited state, which is responsible for the luminescence behavior of complex 1, is a Jahn-Teller distortion for only one of the Au(I) centers together with a gold-gold distance shortening. This behavior could be extrapolated to other phosphorescent dinuclear three-coordinate Au(I) complexes.

Phosphorescent excited state of [Au2[(Ph2Sb)2O]3]2+: Jahn-Teller distortion at only one gold(I) center. Publishing Authors By Initials

VR Bojan,EJ ,A Laguna,JM ,M Monge,ME Olmos,C Silvestru,

For similar organic chemicals: organometallic compounds research abstracts see: organic chemicals: organometallic compounds research

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Phosphorescent excited state of [Au2[(Ph2Sb)2O]3]2+: Jahn-Teller distortion at only one gold(I) center. Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: Journal of the American Chemical Society

VOLUME: 127

Page Numbers: 11564-5

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 24

MONTH: Aug

YEAR: 2005

Phosphorescent excited state of [Au2[(Ph2Sb)2O]3]2+: Jahn-Teller distortion at only one gold(I) center. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

Phosphorescent excited state of [Au2[(Ph2Sb)2O]3]2+: Jahn-Teller distortion at only one gold(I) center. Keywords Mesh Terms:

KEYWORDS: Organometallic Compounds

MESH TERMS: radiation effects

Chemical & Substance for Abstract: Phosphorescent excited state of [Au2[(Ph2Sb)2O]3]2+: Jahn-Teller distortion at only one gold(I) center. Information

Substance Name: Gold

Registry Number: 7440-57-5

Grant and Affiliation Information for Phosphorescent excited state of [Au2[(Ph2Sb)2O]3]2+: Jahn-Teller distortion at only one gold(I) center.

AFFILIATION: Facultatea de Chimie si Inginerie Chimica, Universitatea Babes-Bolyai, RO-400028 Cluj-Napoca, Romania.

Country: United States

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MEDLINETA: J Am Chem Soc

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