Pd-catalyzed alkyl to aryl migration and cyclization: an efficient synthesis of fused polycycles via multiple C-H activation.

Pd-catalyzed alkyl to aryl migration and cyclization: an efficient synthesis of fused polycycles via multiple C-H activation. Research Abstract Details 

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Pd-catalyzed alkyl to aryl migration and cyclization: an efficient synthesis of fused polycycles via multiple C-H activation. Abstract Text:

Qinhua Huang,Alessia Fazio,Guangxiu Dai,Marino A Campo,Richard C Larock,

A novel palladium migration methodology for the synthesis of complex fused polycycles has been developed. This process involves 1,4-palladium alkyl to aryl migrations via through-space C-H activation, followed by intramolecular arylation or an intermolecular Heck reaction providing a very efficient way to synthesize fused ring systems.

Pd-catalyzed alkyl to aryl migration and cyclization: an efficient synthesis of fused polycycles via multiple C-H activation. Publishing Authors By Initials

Q Huang,A Fazio,G Dai,MA Campo,RC Larock,

For similar polycyclic compounds research abstracts see: polycyclic compounds research

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Pd-catalyzed alkyl to aryl migration and cyclization: an efficient synthesis of fused polycycles via multiple C-H activation. Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: Journal of the American Chemical Society

VOLUME: 126

Page Numbers: 7460-1

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 23

MONTH: Jun

YEAR: 2004

Pd-catalyzed alkyl to aryl migration and cyclization: an efficient synthesis of fused polycycles via multiple C-H activation. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

Pd-catalyzed alkyl to aryl migration and cyclization: an efficient synthesis of fused polycycles via multiple C-H activation. Keywords Mesh Terms:

KEYWORDS: Polycyclic Compounds

MESH TERMS: chemistry

Chemical & Substance for Abstract: Pd-catalyzed alkyl to aryl migration and cyclization: an efficient synthesis of fused polycycles via multiple C-H activation. Information

Substance Name: Palladium

Registry Number: 7440-05-3

Grant and Affiliation Information for Pd-catalyzed alkyl to aryl migration and cyclization: an efficient synthesis of fused polycycles via multiple C-H activation.

AFFILIATION: Department of Chemistry, Iowa State University, Ames, Iowa 50011, USA.

Country: United States

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MEDLINETA: J Am Chem Soc

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