Paramagnetic active site models for the molybdenum-copper carbon monoxide dehydrogenase.

Paramagnetic active site models for the molybdenum-copper carbon monoxide dehydrogenase. Research Abstract Details 

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Paramagnetic active site models for the molybdenum-copper carbon monoxide dehydrogenase. Abstract Text:

Craig Gourlay,David J Nielsen,Jonathan M White,Sushilla Z Knottenbelt,Martin L Kirk,Charles G Young,

New paramagnetic, heterobimetallic Mo/Cu complexes featuring the Mo(=O)(mu-S)Cu core of O. carboxidovorans carbon monoxide dehydrogenase have been synthesized and structurally and spectroscopically characterized. The complexes exhibit EPR spectra (left graphic) indicative of extensive electron delocalization across the Mo-S-Cu core, in agreement with computational studies identifying the singly-occupied molecular orbital (right graphic).

Paramagnetic active site models for the molybdenum-copper carbon monoxide dehydrogenase. Publishing Authors By Initials

C Gourlay,DJ Nielsen,JM White,SZ Knottenbelt,ML Kirk,CG Young,

For similar macromolecular substances: multiprotein complexes: multienzyme complexes research abstracts see: macromolecular substances: multiprotein complexes: multienzyme complexes research

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Paramagnetic active site models for the molybdenum-copper carbon monoxide dehydrogenase. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Journal of the American Chemical Society

VOLUME: 128

Page Numbers: 2164-5

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 22

MONTH: Feb

YEAR: 2006

Paramagnetic active site models for the molybdenum-copper carbon monoxide dehydrogenase. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

Paramagnetic active site models for the molybdenum-copper carbon monoxide dehydrogenase. Keywords Mesh Terms:

KEYWORDS: Multienzyme Complexes

MESH TERMS: metabolism

Chemical & Substance for Abstract: Paramagnetic active site models for the molybdenum-copper carbon monoxide dehydrogenase. Information

Substance Name: carbon monoxide dehydrogenase

Registry Number: EC 1.2.99.2

Grant and Affiliation Information for Paramagnetic active site models for the molybdenum-copper carbon monoxide dehydrogenase.

AFFILIATION: School of Chemistry, University of Melbourne, Victoria 3010, Australia.

Country: United States

AGENCY: United States NIGMS

GRANT: GM 057378

ACRONYM: GM

MEDLINETA: J Am Chem Soc

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