Palladium-catalyzed silylation of aryl chlorides with hexamethyldisilane.

Palladium-catalyzed silylation of aryl chlorides with hexamethyldisilane. Research Abstract Details 

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Palladium-catalyzed silylation of aryl chlorides with hexamethyldisilane. Abstract Text:

Eric McNeill,Timothy E Barder,Stephen L Buchwald,

A method for the palladium-catalyzed silylation of aryl chlorides has been developed. The method affords desired product in good yield, is tolerant of a variety of functional groups, and provides access to a wide variety of aryltrimethylsilanes from commercially available aryl chlorides. Additionally, a one-pot procedure that converts aryl chlorides into aryl iodides has been developed.

Palladium-catalyzed silylation of aryl chlorides with hexamethyldisilane. Publishing Authors By Initials

E McNeill,TE Barder,SL Buchwald,

For similar inorganic chemicals: silicon compounds: silanes research abstracts see: inorganic chemicals: silicon compounds: silanes research

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Palladium-catalyzed silylation of aryl chlorides with hexamethyldisilane. Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: Organic letters

VOLUME: 9

Page Numbers: 3785-8

Journal Abbreviation: Org. Lett.

ISSN: 1523-7060

DAY: 18

MONTH: 08

YEAR: 2007

Palladium-catalyzed silylation of aryl chlorides with hexamethyldisilane. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 100890393

Palladium-catalyzed silylation of aryl chlorides with hexamethyldisilane. Keywords Mesh Terms:

KEYWORDS: Silanes

MESH TERMS: chemistry

Chemical & Substance for Abstract: Palladium-catalyzed silylation of aryl chlorides with hexamethyldisilane. Information

Substance Name: Iodine

Registry Number: 7553-56-2

Grant and Affiliation Information for Palladium-catalyzed silylation of aryl chlorides with hexamethyldisilane.

AFFILIATION: Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

Country: United States

AGENCY: United States NIGMS

GRANT: GM-058160

ACRONYM: GM

MEDLINETA: Org Lett

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