Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II).

Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II). Research Abstract Details 

Research Abstract Table of Contents

Jump to the:

Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II). Abstract Text:

Ken-ichi Fujita,Makoto Yamashita,Florian Puschmann,Miguel Martinez Alvarez-Falcon,Christopher D Incarvito,John F Hartwig,Ken-ichi Fujita,Makoto Yamashita,Florian Puschmann,Miguel Martinez Alvarez-Falcon,Christopher D Incarvito,John F Hartwig,

Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II). Publishing Authors By Initials

K Fujita,M Yamashita,F Puschmann,MM Alvarez-Falcon,CD Incarvito,JF Hartwig,K Fujita,M Yamashita,F Puschmann,MM Alvarez-Falcon,CD Incarvito,JF Hartwig,

For similar inorganic chemicals: elements: metals, heavy: palladium research abstracts see: inorganic chemicals: elements: metals, heavy: palladium research

PUBMED ID PMID:

MEDLINE DATE:

Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II). Journal Published:

PUBLICATION TYPE: Research Support, N.I.H., Extr

Journal: Journal of the American Chemical Society

VOLUME: 128

Page Numbers: 9044-5

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 19

MONTH: Jul

YEAR: 2006

Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II). Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 7503056

Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II). Keywords Mesh Terms:

KEYWORDS: Palladium

MESH TERMS: chemistry

Chemical & Substance for Abstract: Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II). Information

Substance Name: Palladium

Registry Number: 7440-05-3

Grant and Affiliation Information for Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II).

AFFILIATION: Department of Chemistry, Yale University, P.O. Box 208107, New Haven, Connecticut 06520-8107, USA.

Country: United States

AGENCY: United States NIGMS

GRANT: GM-58108

ACRONYM: GM

MEDLINETA: J Am Chem Soc

REFSOURCE:

DATABASENAME:

ACCESSION NUMBER:

Number Hits: 0

Organometallic chemistry of amidate complexes accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladiumII Related Publications

• A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes.
• Direct measurement of the thermodynamics of vinylarene hydroamination.
• Direct, catalytic hydroaminoalkylation of unactivated olefins with N-alkyl arylamines.
• Directly observed transmetalation from boron to rhodium. beta-aryl elimination from Rh(I) arylboronates and diarylborinates.
• Distinct thermodynamics for the formation and cleavage of N-H bonds in aniline and ammonia. Directly-observed reductive elimination of ammonia from an isolated amido hydride complex.
• Enantioselective alpha-Arylation of Ketones with Aryl Triflates Catalyzed by Difluorphos Complexes of Palladium and Nickel.
• Experimental and computational evidence for a boron-assisted, sigma-bond metathesis pathway for alkane borylation.
• Highly efficient and functional-group-tolerant catalysts for the palladium-catalyzed coupling of aryl chlorides with thiols.
• Hydroamination and hydroalkoxylation catalyzed by triflic acid. Parallels to reactions initiated with metal triflates.
• Lewis acid acceleration of C-N bond-forming reductive elimination from heteroarylpalladium complexes and catalytic amidation of heteroaryl bromides.
• Meta Halogenation of 1,3-Disubstituted Arenes via Iridium-Catalyzed Arene Borylation.
• Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate.
• Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II).
• Oxidative addition of aryl tosylates to palladium(0) and coupling of unactivated aryl tosylates at room temperature.
• Palladium-catalyzed coupling of ammonia and lithium amide with aryl halides.
• Palladium-catalyzed synthesis of aryl ketones by coupling of aryl bromides with an acyl anion equivalent.
• Plasma concentrations of the HIV-protease inhibitor lopinavir are suboptimal in children aged 2 years and below.
• Primary tert- and sec-allylamines via palladium-catalyzed hydroamination and allylic substitution with hydrazine and hydroxylamine derivatives.
• Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex.
• Regio- and enantioselective iridium-catalyzed intermolecular allylic etherification of achiral allylic carbonates with phenoxides.
• Regioselective and enantioselective iridium-catalyzed allylation of enamines.
• Relative rates for the amination of eta3-allyl and eta3-benzyl complexes of palladium.
• Resting state and kinetic studies on the asymmetric allylic substitutions catalyzed by iridium-phosphoramidite complexes.
• Rhodium-catalyzed anti-Markovnikov hydroamination of vinylarenes.
• Rhodium-catalyzed intramolecular, anti-Markovnikov hydroamination. Synthesis of 3-arylpiperidines.
• Ruthenium-catalyzed regiospecific borylation of methyl C-H bonds.
• Tropene derivatives by sequential intermolecular and transannular, intramolecular palladium-catalyzed hydroamination of cycloheptatriene.
• [Diagnosis of thymoma.]
• [Histologic and histomorphometric follow-up observations of osseointegration of corundum-blasted BMP-3 coated titanium test implants (Ti6Al4V) at orthotopic site in the giant rabbit]
• [Hyperostosis frontalis interna.]