One-pot terminal alkene homologation using a tandem olefin cross-metathesis/allylic carbonate reduction sequence.

One-pot terminal alkene homologation using a tandem olefin cross-metathesis/allylic carbonate reduction sequence. Research Abstract Details 

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One-pot terminal alkene homologation using a tandem olefin cross-metathesis/allylic carbonate reduction sequence. Abstract Text:

Daniel L Comins,Jason M Dinsmore,Lucas R Marks,Daniel L Comins,Jason M Dinsmore,Lucas R Marks,Daniel L Comins,Jason M Dinsmore,Lucas R Marks,

A one-carbon homologation of terminal alkenes has been developed utilizing an olefin cross-metathesis followed by a palladium-mediated allylic carbonate reduction; various substrates were used to demonstrate the scope of the reaction, with yields ranging from 65 to 86%.

One-pot terminal alkene homologation using a tandem olefin cross-metathesis/allylic carbonate reduction sequence. Publishing Authors By Initials

DL Comins,JM Dinsmore,LR Marks,DL Comins,JM Dinsmore,LR Marks,DL Comins,JM Dinsmore,LR Marks,

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One-pot terminal alkene homologation using a tandem olefin cross-metathesis/allylic carbonate reduction sequence. Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: Chemical communications (Cambridge, England)

VOLUME:

Page Numbers: 4170-1

Journal Abbreviation: Chem. Commun. (Camb.)

ISSN: 1359-7345

DAY: 7

MONTH: 08

YEAR: 2007

One-pot terminal alkene homologation using a tandem olefin cross-metathesis/allylic carbonate reduction sequence. Information

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LANGUAGE: eng

NlmUniqueID: 9610838

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Grant and Affiliation Information for One-pot terminal alkene homologation using a tandem olefin cross-metathesis/allylic carbonate reduction sequence.

AFFILIATION: Department of Chemistry, North Carolina State University, Raleigh, NC, USA. Daniel_Comins@ncsu.edu

Country: England

AGENCY: United States NIGMS

GRANT: GM 34442

ACRONYM: GM

MEDLINETA: Chem Commun (Camb)

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