The development of high-load, oligomeric benzylsulfonium salts, generated via ring-opening metathesis polymerization, and their utility in facile benzylations of various nucleophiles is reported. These oligomeric sulfonium salts exist as free-flowing powders and are stable at room temperature. After the benzylation event, purification is attained via simple dry load/filtration, followed by solvent removal to deliver products in excellent yield and purity.
Oligomeric benzylsulfonium salts: facile benzylation via high-load ROMP reagents. Publishing Authors By Initials
Oligomeric benzylsulfonium salts: facile benzylation via high-load ROMP reagents. Journal Published:
PUBLICATION TYPE: Research Support, Non-U.S. Gov
Journal: The Journal of organic chemistry
VOLUME: 72
Page Numbers: 3194-8
Journal Abbreviation:
ISSN: 0022-3263
DAY: 4
MONTH: 04
YEAR: 2007
Oligomeric benzylsulfonium salts: facile benzylation via high-load ROMP reagents. Information
Number of References:
LANGUAGE: eng
NlmUniqueID: 2985193
Oligomeric benzylsulfonium salts: facile benzylation via high-load ROMP reagents. Keywords Mesh Terms:
KEYWORDS: Salts
MESH TERMS: chemistry
Chemical & Substance for Abstract: Oligomeric benzylsulfonium salts: facile benzylation via high-load ROMP reagents. Information
Substance Name: phenylmethanesulfonic acid
Registry Number: 100-87-8
Grant and Affiliation Information for Oligomeric benzylsulfonium salts: facile benzylation via high-load ROMP reagents.
AFFILIATION: The Center for Chemical Methodologies and Library Development at the University of Kansas, and Department of Chemistry, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, Kansas 66045-7582, USA.
Country: United States
AGENCY: United States NIGMS
GRANT: P41 GM076302
ACRONYM: GM
MEDLINETA: J Org Chem
REFSOURCE:
DATABASENAME:
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