Nucleophilic substitution reactions of sulfur-substituted cyclohexanone acetals: an analysis of the factors controlling stereoselectivity.

Nucleophilic substitution reactions of sulfur-substituted cyclohexanone acetals: an analysis of the factors controlling stereoselectivity. Research Abstract Details 

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Nucleophilic substitution reactions of sulfur-substituted cyclohexanone acetals: an analysis of the factors controlling stereoselectivity. Abstract Text:

Susan B Billings,K A Woerpel,

The reactions of cyclohexanone acetals substituted with thiophenyl groups (and other heteroatoms) at C-2 demonstrate the powerful influence that these substituents have on the stereoselectivity of nucleophilic substitution reactions. The trans selectivities of these reactions correlate with the behavior of the corresponding ketones. These experiments lend support to the possibility that the reactions of the acetals, which proceed via oxocarbenium ions, are operating under Felkin-Anh control.

Nucleophilic substitution reactions of sulfur-substituted cyclohexanone acetals: an analysis of the factors controlling stereoselectivity. Publishing Authors By Initials

SB Billings,KA Woerpel,

For similar inorganic chemicals: sulfur compounds research abstracts see: inorganic chemicals: sulfur compounds research

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Nucleophilic substitution reactions of sulfur-substituted cyclohexanone acetals: an analysis of the factors controlling stereoselectivity. Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: The Journal of organic chemistry

VOLUME: 71

Page Numbers: 5171-8

Journal Abbreviation: J. Org. Chem.

ISSN: 0022-3263

DAY: 7

MONTH: Jul

YEAR: 2006

Nucleophilic substitution reactions of sulfur-substituted cyclohexanone acetals: an analysis of the factors controlling stereoselectivity. Information

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LANGUAGE: eng

NlmUniqueID: 2985193

Nucleophilic substitution reactions of sulfur-substituted cyclohexanone acetals: an analysis of the factors controlling stereoselectivity. Keywords Mesh Terms:

KEYWORDS: Sulfur Compounds

MESH TERMS: chemistry

Chemical & Substance for Abstract: Nucleophilic substitution reactions of sulfur-substituted cyclohexanone acetals: an analysis of the factors controlling stereoselectivity. Information

Substance Name: Sulfur Compounds

Registry Number: 0

Grant and Affiliation Information for Nucleophilic substitution reactions of sulfur-substituted cyclohexanone acetals: an analysis of the factors controlling stereoselectivity.

AFFILIATION: Department of Chemistry, University of California, Irvine, CA 92696-2025, USA.

Country: United States

AGENCY: United States NIGMS

GRANT: GM 61066

ACRONYM: GM

MEDLINETA: J Org Chem

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