Nuclear spin selection rules for reactive collision systems by the spin-modification probability method.

Nuclear spin selection rules for reactive collision systems by the spin-modification probability method. Research Abstract Details 

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Nuclear spin selection rules for reactive collision systems by the spin-modification probability method. Abstract Text:

Kisam Park,John C Light,Kisam Park,John C Light,Kisam Park,John C Light,

The spin-modification probability (SMP) method, which provides fundamental and detailed quantitative information on the nuclear spin selection rules, is discussed more systematically and generalized for reactive collision systems involving more than one configuration of reactant and product molecules, explicitly taking account of the conservation of the overall nuclear spin symmetry as well as the conservation of the total nuclear spin angular momentum, under the assumption of no nuclear hyperfine interaction. The values of SMP once calculated can be used for any system of identical nuclei of any spin as long as the system has the corresponding nuclear spin symmetry. The values of SMP calculated for simple systems can also be used for more complex systems containing several kinds of identical nuclei or various isotopomers. The generalized formulation of statistical scattering theory which can easily represent various rearrangement mechanisms is also presented.

Nuclear spin selection rules for reactive collision systems by the spin-modification probability method. Publishing Authors By Initials

K Park,JC Light,K Park,JC Light,K Park,JC Light,

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Nuclear spin selection rules for reactive collision systems by the spin-modification probability method. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: The Journal of chemical physics

VOLUME: 127

Page Numbers: 224101

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ISSN: 0021-9606

DAY: 14

MONTH: Dec

YEAR: 2007

Nuclear spin selection rules for reactive collision systems by the spin-modification probability method. Information

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LANGUAGE: eng

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Grant and Affiliation Information for Nuclear spin selection rules for reactive collision systems by the spin-modification probability method.

AFFILIATION: Department of Chemistry, University of Chicago, Chicago, Illinois 60637, USA and James Franck Institute, University of Chicago, Chicago, Illinois 60637, USA.

Country: United States

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MEDLINETA: J Chem Phys

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