Novel synthesis and characterization of five isomers of (C(70))(2) fullerene dimers.

Novel synthesis and characterization of five isomers of (C(70))(2) fullerene dimers. Research Abstract Details 

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Novel synthesis and characterization of five isomers of (C(70))(2) fullerene dimers. Abstract Text:

Grant S Forman,Nikos Tagmatarchis,Hisanori Shinohara,

The synthesis and characterization of dimers and polymers, wherein two or more cages are linked, represent an important frontier in the chemistry of fullerene derivatives. A simple and novel method that requires no special apparatus has been developed for the dimerization of [70]fullerene to (C70)2. Upon grinding [70]fullerene in a mortar and pestle in the presence of K2CO3, five structural isomers of (C70)2 have been produced. These isomers are separated from one another via high performance liquid chromatography and are characterized by 13C NMR, UV-vis-NIR absorption and mass spectroscopy.

Novel synthesis and characterization of five isomers of (C(70))(2) fullerene dimers. Publishing Authors By Initials

GS Forman,N Tagmatarchis,H Shinohara,

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Novel synthesis and characterization of five isomers of (C(70))(2) fullerene dimers. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 124

Page Numbers: 178-9

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 16

MONTH: Jan

YEAR: 2002

Novel synthesis and characterization of five isomers of (C(70))(2) fullerene dimers. Information

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LANGUAGE: eng

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Grant and Affiliation Information for Novel synthesis and characterization of five isomers of (C(70))(2) fullerene dimers.

AFFILIATION: Nagoya University, Department of Chemistry, Nagoya 464-8602, Japan.

Country: United States

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MEDLINETA: J Am Chem Soc

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