Three experimental self-etching primers - consisting of N-methacryloyl-omega-aminoalkyl phosphonic acid (NMomegaP) with different methylene chain lengths and N-methacryloyl glycine (NMGly) - were formulated. The influence of methylene chain length in NMomegaP derivatives on the chemical nature of calcium salts was examined following their application to tooth components. Bond strengths of experimental self-etching primers created with these monomers to enamel and dentin were also investigated. Nuclear magnetic resonance spectroscopy showed that NMomegaPs decalcified tooth components with formation of calcium salts, which changed from calcium hydrogen phosphonate to calcium phosphonate with increase in methylene chain length within the NMomegaP structure. Disparity in calcium salt formation was related to increases in bond strength to enamel from 18 to 24 MPa. However, bond strength to dentin remained unchanged (22 MPa). The relative dependency of bond strength on monomer methylene chain length was probably attributable to the sites where these NMomegaP calcium salts had deposited on the bonding substrates.
NMR study on the adhesion efficacy of experimental phosphonic acid monomers. Publishing Authors By Initials
NMR study on the adhesion efficacy of experimental phosphonic acid monomers. Journal Published:
PUBLICATION TYPE: Research Support, Non-U.S. Gov
Journal: Dental materials journal
VOLUME: 26
Page Numbers: 382-7
Journal Abbreviation:
ISSN: 0287-4547
DAY: 3
MONTH: May
YEAR: 2007
NMR study on the adhesion efficacy of experimental phosphonic acid monomers. Information
Number of References:
LANGUAGE: eng
NlmUniqueID: 8309299
NMR study on the adhesion efficacy of experimental phosphonic acid monomers. Keywords Mesh Terms:
KEYWORDS: Phosphonic Acids
MESH TERMS: pharmacology
Chemical & Substance for Abstract: NMR study on the adhesion efficacy of experimental phosphonic acid monomers. Information
Substance Name: Glycine
Registry Number: 56-40-6
Grant and Affiliation Information for NMR study on the adhesion efficacy of experimental phosphonic acid monomers.
AFFILIATION: Department of Dental Biomaterials, Nihon University School of Dentistry at Matsudo, 870-1 Sakaecho, Nishi 2, Matsudo, Chiba 271-8587, Japan. nishiyama.norihiro@nihon-u.ac.jp
Country: Japan
AGENCY: United States NIDCR
GRANT: R01 DE 014911
ACRONYM: DE
MEDLINETA: Dent Mater J
REFSOURCE:
DATABASENAME:
ACCESSION NUMBER:
Number Hits: 0
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