Just like transition metal complexes, N-heterocyclic carbenes (NHCs) promote the aggregation of white phosphorus (P4) as shown by the high yield synthesis of a P12 cluster capped by two NHCs. The nuclearity observed is equal to that of the largest phosphorus cluster prepared using transition metals, but the architecture of the P12 core is entirely novel.
NHC-Mediated Aggregation of P(4): Isolation of a P(12) Cluster. Publishing Authors By Initials
NHC-Mediated Aggregation of P(4): Isolation of a P(12) Cluster. Journal Published:
PUBLICATION TYPE: Journal Article
Journal: Journal of the American Chemical Society
VOLUME: 129
Page Numbers: 14180-1
Journal Abbreviation: J. Am. Chem. Soc.
ISSN: 0002-7863
DAY: 31
MONTH: 10
YEAR: 2007
NHC-Mediated Aggregation of P(4): Isolation of a P(12) Cluster. Information
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LANGUAGE: eng
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AFFILIATION: UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California Riverside, Riverside, California 92521-0403.
Country: United States
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MEDLINETA: J Am Chem Soc
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